Me3Si(C13H6(Me)2B(2,4,6-triisopropylphenyl))2C13H6Me2SiMe3 | 1300617-89-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: Me3Si(C13H6(Me)2B(2,4,6-triisopropylphenyl))2C13H6Me2SiMe3
• CAS: 1300617-89-3
• 化学式: C₈₁H₁₀₀B₂Si₂
• 分子量: 1151.48
• InChiKey: INPGFGLVPSYFNU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  17.47
• 重原子数：
  85.0
• 可旋转键数：
  14.0
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  Me3Si(C13H6(Me)2B(2,4,6-triisopropylphenyl))2C13H6Me2SiMe3 在 三溴化硼 作用下， 以 二氯甲烷 为溶剂， 以76%的产率得到Br₂B(C₁₃H₆(Me)2B(2,4,6-triisopropylphenyl))2C₁₃H₆Me₂BBr₂
  参考文献：
  名称：

  Applying the Oligomer Approach to Luminescent Conjugated Organoboranes

  摘要：

  A series of highly luminescent monodisperse fluoreneborane oligomers (n = 1-6) were prepared using a new iterative synthetic procedure that takes advantage of the highly selective and differential reactivity of bromoboranes with arylsilanes and arylstannanes. Cyclic and square wave voltammetry revealed a gradual decrease of the LUMO energy levels with increasing chain length, while absorption and emission data showed a bathochromic shift and increase in quantum efficiency. An extended conjugation length of n(ECL) = S was derived.

  DOI：

  10.1021/ja201436a
• 作为产物：
  描述：

  2,7-二溴-9,9-二甲基芴 在 正丁基锂 、 四甲基乙二胺 、 三溴化硼 作用下， 以 乙醚 、 二氯甲烷 、 甲苯 为溶剂， 反应 48.0h， 生成 Me3Si(C13H6(Me)2B(2,4,6-triisopropylphenyl))2C13H6Me2SiMe3
  参考文献：
  名称：

  Applying the Oligomer Approach to Luminescent Conjugated Organoboranes

  摘要：

  A series of highly luminescent monodisperse fluoreneborane oligomers (n = 1-6) were prepared using a new iterative synthetic procedure that takes advantage of the highly selective and differential reactivity of bromoboranes with arylsilanes and arylstannanes. Cyclic and square wave voltammetry revealed a gradual decrease of the LUMO energy levels with increasing chain length, while absorption and emission data showed a bathochromic shift and increase in quantum efficiency. An extended conjugation length of n(ECL) = S was derived.

  DOI：

  10.1021/ja201436a

文献信息

• Highly Luminescent, Electron-Deficient Bora-cyclophanes
  作者：Pangkuan Chen、Frieder Jäkle

  DOI：10.1021/ja209602z

  日期：2011.12.21

  A highly luminescent conjugated organoboron macrocycle containing six Lewis acidic boron centers was synthesized. Comparison of the optical and electronic properties with those of a hexameric linear oligomer revealed important differences due to delocalization within the highly symmetric cyclic conjugated structure. Exposure of this unique electron-deficient bora-cyclophane to fluoride or cyanide results in amplified fluorescence quenching and can be exploited to switch between an electron-deficient macrocycle and a highly charged, electron-rich borate cycle.