[(Diethylphosphinothioylamino)-phenylphosphinothioyl]benzene | 42847-87-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(Diethylphosphinothioylamino)-phenylphosphinothioyl]benzene
• CAS: 42847-87-0
• 化学式: C₁₆H₂₁NP₂S₂
• 分子量: 353.429
• InChiKey: AKPJCTHEOPLCKB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  76.2
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 [(Diethylphosphinothioylamino)-phenylphosphinothioyl]benzene 在 KOC(CH₃)3 作用下， 以 甲醇 为溶剂， 以58%的产率得到[[diethyl(sulfido)-λ5-phosphanylidene]amino]-diphenyl-sulfanylidene-λ5-phosphane;platinum(2+)
  参考文献：
  名称：

  The preparation and coordination chemistry of R2P(S)NHP(S)R′2 (R and R′=iPr, Ph, Et, OEt or OPh)

  摘要：

  The preparation of R2P(S)NHP(S)R-2' (R and R' ='Pr, Ph, Et, Oft or OPh) is reported. Four examples have been characterised crystallographically. The molecules exist with a twisted P=S . . .P=S arrangement and hydrogen bond in the solid state. The H-bonding is influenced by the nature of the R groups; thus R = alkyl are better donors than R = aryl. Demonstrative metal complexes of zinc, palladium and platinum are also reported. Interestingly, the palladium and platinum complexes show a consistent conformational difference with PdS2P2N pseudo-boat conformations and PtS2P2N pseudo-chair conformations. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00602-1