decane-1,10-diylbis(trihexylphosphonium) dodecanedioate | 955363-21-0

• 分子结构分类: 有机化合物
• 英文名称: decane-1,10-diylbis(trihexylphosphonium) dodecanedioate
• CAS: 955363-21-0
• 化学式: C₁₂H₂₀O₄*C₄₆H₉₈P₂
• 分子量: 941.52
• InChiKey: IETFDUCFYXLULJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  18.01
• 重原子数：
  64.0
• 可旋转键数：
  52.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.97
• 拓扑面积：
  80.26
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  dodecanodioic acid silver salt 、 1,10-di(trihexylphosphonium chloride)decane 生成 decane-1,10-diylbis(trihexylphosphonium) dodecanedioate
  参考文献：
  名称：

  Synthesis and Properties of Supramolecular Ionic Networks

  摘要：

  The synthesis of a supramolecular ionic network, its physical properties, and the use of this network property to form macroscopic porphyrin fibers are described. These ionic networks are compared to ionic liquids. Current ionic liquid compositions have a charge and molar ratio of 1:1 where an anionic species is matched with a cationic species; however, alteration of this molar ratio while maintaining the charge ratio of 1:1 by using multivalent cationic/anionic molecular pairs affords new ionically cross-linked networks with interesting properties.

  DOI：

  10.1021/ja803248q

文献信息

• Ionic viscoelastics and viscoelastic salts
  申请人：Grinstaff Mark W.

  公开号：US08367845B2

  公开（公告）日：2013-02-05

  One embodiment of the present invention relates to ionic liquids and ionic viscoelastics formed between [1] a small molecule or macromolecule containing two or more cations; and [2] a small molecule or macromolecule containing two or more anions. Another embodiment of the invention is the use of the inventive ionic liquids and ionic viscoelastics, formed between a small molecule or macromolecule containing two or more cations and a small molecule or macromolecule containing two or more anions, to form a crosslinked network. In certain embodiments, the ionic liquids formed can be viscous liquids, viscous liquid formed networks, or viscoelastic networks/gels. In certain embodiments, the ionic material of the invention may be used for a variety of applications including, but not limited to, lubricants, additives, gas separation, liquid separation, membranes, fuel cells, sensors, batteries, coatings, heat storage, liquid crystals, biocompatible fluids, solvents, and electronic materials.

  本发明的一个实施例涉及由以下两种物质形成的离子液体和离子粘弹性体：（1）含有两个或两个以上阳离子的小分子或大分子；以及（2）含有两个或两个以上阴离子的小分子或大分子。发明的另一个实施例是利用本发明的含有两个或两个以上阳离子的小分子或大分子和含有两个或两个以上阴离子的小分子或大分子之间形成的离子液体和离子粘弹性体制成交联网络。在某些实施例中，可以形成粘稠液体、形成的粘稠液体网络或粘弹性网络/凝胶。在某些实施例中，本发明的离子材料可用于多种应用，包括但不限于润滑剂、添加剂、气体分离、液体分离、膜、燃料电池、传感器、电池、涂料、热储存、液晶、生物相容性流体、溶剂和电子材料。