poly[[bis(pyridine-κN)copper(II)]-μ3-5-hydroxyisophthalato-κ3O:O':O''] | 847869-90-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: poly[[bis(pyridine-κN)copper(II)]-μ3-5-hydroxyisophthalato-κ3O:O':O'']
• CAS: 847869-90-3
• 化学式: C₁₈H₁₄CuN₂O₅
• 分子量: 401.866
• InChiKey: PMAFEWBEYXEPLS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吡啶 、 5-羟基间苯二甲酸 、 copper(II) acetate monohydrate 在 NaOH 作用下， 以 水 为溶剂， 以56.2%的产率得到poly[[bis(pyridine-κN)copper(II)]-μ3-5-hydroxyisophthalato-κ3O:O':O'']
  参考文献：
  名称：

  Poly[[bis(pyridine-κN)copper(II)]-μ₃-5-hydroxyisophthalato-κ³O:O′:O′′]

  摘要：

  In the title compound, [Cu(C8H4O5)(C5H5N)(2)](n) or [Cu(OH-BDC)( py)(2)](n) (where OH-H2BDC is 5-hydroxyisophthalic acid and py is pyridine), the Cu atoms are coordinated by two N atoms from the pyridine ligands and by three O atoms from hydroxyisophthalate ligands in a highly distorted triangular bipyramidal environment, with Cu - O distances in the range 1.941 (4) - 2.225 (5) Angstrom and Cu - N distances of 2.014 (6) and 2.046 (6) Angstrom. The [Cu(OH-BDC)](n) two-dimensional network is built up from interlocking 22-, 15- and eight-membered rings via sharing of Cu atoms and O - H ... O hydrogen bonds. Consolidation of the packing structure is achieved by edge- or point-to-face C - H ...pi interactions and offset or slipped pi-pi stacking interactions.

  DOI：

  10.1107/s0108270104027660