aqua[N,N'-bis(3,5-dichlorosalicylidene)ethylenediaminato-κ4O,N,N',O'](methanol-κO)manganese(III) perchlorate | 869090-65-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: aqua[N,N'-bis(3,5-dichlorosalicylidene)ethylenediaminato-κ4O,N,N',O'](methanol-κO)manganese(III) perchlorate
• CAS: 869090-65-3
• 化学式: C₁₇H₁₆Cl₄MnN₂O₄*ClO₄
• 分子量: 608.526
• InChiKey: UGEHKEHNEJDBCV-SVKFYUCWSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 sodium perchlorate monohydrate 、 manganese(III) triacetate dihydrate 、 乙二胺 、 3,5-二氯水杨醛 以 甲醇 为溶剂， 生成 aqua[N,N'-bis(3,5-dichlorosalicylidene)ethylenediaminato-κ4O,N,N',O'](methanol-κO)manganese(III) perchlorate
  参考文献：
  名称：

  Diaqua[N,N′-bis(5-methoxysalicylidene)ethylenediaminato-κ⁴O,N,N′,O′]manganese(III) perchlorate, aqua[N,N′-bis(3,5-dichlorosalicylidene)ethylenediaminato-κ⁴O,N,N′,O′](methanol-κO)manganese(III) perchlorate and bis[μ-N,N′-bis(3-methoxysalicylidene)ethylenediaminato-κ⁵O,N,N′,O′:O]bis[(methanol-κO)manganese(III)] diperchlorate

  摘要：

  The title compounds, a hydrogen-bonded linear chain, [Mn( C18H18N2O4)(H2O)(2)] ClO4, ( I), a hydrogen-bonded pseudodimer, [ Mn(C16H10Cl4N2O2)(CH4O)(H2O)] ClO4, ( II), and a dimer, [Mn-2(C18H18N2O4)(2)(CH4O)(2)](ClO4)(2), ( III), respectively, have been structurally characterized. The three complexes are completely different in their structural features, despite identical counter-anions and only slight modification of the substituents in the ligands. Complex ( I) affords an elongated octahedral coordination environment, with axial Mn O( water) distances of 2.259 ( 3) and 2.313 ( 3) angstrom, which forms hydrogen-bonded linear chains along the crystallographic c axis. Hydrogen-bonded pseudo-dimeric compound ( II) also affords an elongated octahedral coordination environment, with axial Mn - O(CH3OH)= 2.222 ( 3) angstrom and Mn - O( water) = 2.266 ( 3) angstrom. Dimeric complex ( III) is centrosymmetric and consists of distorted octahedral Mn atoms, with axial Mn O( CH3OH)= 2.242 ( 2) angstrom and Mn - O( phenolate)= 2.348 ( 1) angstrom, connected via bridging O atoms from one of the ligands. The magnetic properties of the three complexes are described.

  DOI：

  10.1107/s0108270105013545