9-{(1E)-hexenyl}anthracene | 1311408-28-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 9-{(1E)-hexenyl}anthracene
• 英文别名: 9-[(E)-hex-1-enyl]anthracene
• CAS: 1311408-28-2
• 化学式: C₂₀H₂₀
• 分子量: 260.379
• InChiKey: ANWAPCSZJIUSJI-LHHJGKSTSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.2
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  反式-1-己烯-1-基硼酸 在 potassium phosphate monohydrate 、 palladium diacetate 、 三环己基膦 作用下， 以 1,4-二氧六环 、 甲苯 为溶剂， 反应 1.33h， 生成 9-{(1E)-hexenyl}anthracene
  参考文献：
  名称：

  Microwave-assisted Suzuki–Miyaura cross-coupling of 2-alkyl and 2-alkenyl-benzo-1,3,2-diazaborolanes

  摘要：

  Nitrogen-based boronate esters, such as 2-octyl-benzo-1,3,2-diazaborolane, 2-phenethyl-benzo-1,3,2-diazaborolane, and 2-{(1E)-hexenyl}-benzo-1,3,2-diazaborolane have been shown to be suitable coupling partners with arylhalides in microwave accelerated Suzuki cross-coupling reactions. Reaction yields of up to 89% were achieved. The use of a silicon group attached to the nitrogen atom, proved to enhance the reactivity of 2-octyl-benzo-1,3,2-diazaborolane. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2011.03.095

文献信息

• Microwave-assisted Suzuki–Miyaura cross-coupling of 2-alkyl and 2-alkenyl-benzo-1,3,2-diazaborolanes
  作者：Siphamandla W. Hadebe、Siphamandla Sithebe、Ross S. Robinson

  DOI：10.1016/j.tet.2011.03.095

  日期：2011.6

  Nitrogen-based boronate esters, such as 2-octyl-benzo-1,3,2-diazaborolane, 2-phenethyl-benzo-1,3,2-diazaborolane, and 2-(1E)-hexenyl}-benzo-1,3,2-diazaborolane have been shown to be suitable coupling partners with arylhalides in microwave accelerated Suzuki cross-coupling reactions. Reaction yields of up to 89% were achieved. The use of a silicon group attached to the nitrogen atom, proved to enhance the reactivity of 2-octyl-benzo-1,3,2-diazaborolane. (C) 2011 Elsevier Ltd. All rights reserved.