[Fe(biphenyl-2,2'-dicarboxylate)(4,4'-bipyridine)]n | 1193397-82-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Fe(biphenyl-2,2'-dicarboxylate)(4,4'-bipyridine)]n
• CAS: 1193397-82-8
• 化学式: C₁₀H₈N₂*C₁₄H₈O₄*Fe
• 分子量: 452.249
• InChiKey: GEHZLNPEXQAGQH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.22
• 重原子数：
  31.0
• 可旋转键数：
  4.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  106.04
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为产物：
  描述：

  4,4'-联吡啶 、 iron(II) chloride tetrahydrate 、 2,2'-联苯二甲酸 在 aq. NaOH 作用下， 以 水 为溶剂， 以63%的产率得到[Fe(biphenyl-2,2'-dicarboxylate)(4,4'-bipyridine)]n
  参考文献：
  名称：

  Mixed-ligand coordination polymers constructed from flexible 2,2′-biphenyldicarboxylate and rigid isomeric bipyridines

  摘要：

  Six coordination polymers have been synthesized and characterized based on dpa and isomeric bipyridine mixed ligands with various metal ions. Complex 1 exhibits a two-dimensional layer structure. Complex 2 is isomorphic to complex 1, with only small differences in bond lengths and bond angles. Complex 3 shows a one-dimensional chain structure composed of interesting pentanuclear Co building units. Complex 4 possesses a two-dimensional (4, 4) layer network, which crystallizes in a homochiral space group. During the synthesis process of complex 4, the dpa ligands decompose and form 2-bpa ligands, which connect with Ni atoms and produce the two-dimensional complex 5. Complex 6 exhibits a three-dimensional supramolecular structural feature constructed from discrete building units with pi-pi interactions. Furthermore, the magnetic properties of complex 2 are studied. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.07.043