cobalt tetra-4-(chlorocarbonyl)phthalocyanine | 73533-44-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: cobalt tetra-4-(chlorocarbonyl)phthalocyanine
• CAS: 73533-44-5
• 化学式: C₃₆H₁₂Cl₄CoN₈O₄
• 分子量: 821.348
• InChiKey: ODNFTGJWVGYQIQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  cobalt tetra-4-(chlorocarbonyl)phthalocyanine 在 sodium azide 作用下， 以 水 为溶剂， 反应 13.0h， 以78%的产率得到[2,9,16,23-tetra(azidocarbonyl)phthalocyanin]cobalt(II)
  参考文献：
  名称：

  Synthesis of the azide derivative of cobalt tetra(carboxy)phthalocyaninate and its immobilization on nonwoven polypropylene

  摘要：

  Methods of the synthesis of cobalt tetra(carboxy)phthalocyaninate azide derivative and its immobilization on nonwoven polypropylene and the structure of the phthalocyaninate on a polypropylene fiber surface were studied.

  DOI：

  10.1134/s107042721109028x
• 作为产物：
  描述：

  四羧基酞菁钴 在 氯化亚砜 作用下， 以 苯 为溶剂， 反应 7.0h， 以98%的产率得到cobalt tetra-4-(chlorocarbonyl)phthalocyanine
  参考文献：
  名称：

  Phthalocyanines and Related Compounds: XXXVII. Synthesis of Covalent Conjugates of Carboxy-substituted Phthalocyanines with α-Amino Acids

  摘要：

  Methods of synthesis of covalent conjugates of metal complexes of octa-4,5-carboxy- and tetra-4-carboxyphthalocyanine, as well as of octa-6,7-carboxy-2,3-naphthalocyanine with alpha-amino acids, glycine and sarcosine, were developed and certain properties of the products were studied. The prepared conjugates are soluble in organic solvents and water.

  DOI：

  10.1023/b:rugc.0000030404.00492.d1

文献信息

• Aerobic oxidation of thioglycol catalysed by metallophthalocyanine in an organic-inorganic hybrid vesicle “cerasome”
  作者：Guolin Zhang、Li Zhang、Dan Zhang、Qiuhua Wu、Yoshihiro Sasaki、Yoshio Hisaeda、Kazuma Yasuhara、Jun-ichi Kikuchi、Xi-Ming Song

  DOI：10.1016/j.inoche.2020.107866

  日期：2020.5

  Abstract A molecular assembly of a hydrophobized metallophthalocyanine derivative embedded in a cerasome, an organic–inorganic hybrid vesicle with a lipid bilayer and silica surface, was a potent catalyst for aerobic oxidation of thioglycol. The catalytic activity was higher than those in hexadecyl 2-hydroxy-3-chloropropyl phosphate vesicles, sodium dodecylsulfate micelles, ethanol, and benzene.

  摘要 嵌入陶瓷体中的疏水化金属酞菁衍生物的分子组装体是一种具有脂质双层和二氧化硅表面的有机-无机杂化囊泡，是硫甘醇有氧氧化的有效催化剂。催化活性高于十六烷基2-羟基-3-氯丙基磷酸酯囊泡、十二烷基硫酸钠胶束、乙醇和苯。