n-tetradecyltriphenylstannane | 330680-72-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: n-tetradecyltriphenylstannane
• CAS: 330680-72-3
• 化学式: C₃₂H₄₄Sn
• 分子量: 547.411
• InChiKey: TUPVHMITEHLSET-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.6
• 重原子数：
  33
• 可旋转键数：
  11
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  n-tetradecyltriphenylstannane 、 水 、 溴 以 氯仿 为溶剂， 生成 bis[di-μ-hydroxobis[fac-tribromoaquotin(IV)]] heptahydrate
  参考文献：
  名称：

  六水合双{di-μ-羟基双（[fac-tribromoaquotin（IV）]}}的合成和晶体结构

  摘要：

  摘要从Br2和Ph3 Sn（CH2）13CH3在空气中的CHCl3溶液中以3：1的摩尔比反应混合物中分离出的产物是双{di-μ-羟基双（fac-tribromoaquotin（IV）]}七水合物，[ Br3（H2O）Sn（μ-OH）2 Sn（O2H）Br3]·7H2O，2 [fac-（1：X = Br）]·7H2O。先前的报道表明，锡配合物[fac-（1：X = Cl或Br）]是通过适当的锡（IV）或锡（II）卤化物的水解或氧化/水解而以各种溶剂化形式获得的。与以前的尝试相比，此处报道的晶体结构确定提供了2 [fac-（1：X = Br）]·7H2O改进的核细度，即[fac-（1：X = Br）]·7H2O。固态结构由中心菱形平面Sn2O2环组成。锡中心具有扭曲的八面体几何形状，每个Br配体都转变为O原子。Br配体转化为aqua配体，

  DOI：

  10.1016/j.ica.2005.04.035
• 作为产物：
  描述：

  tetradecylmagnesium bromide 、 三苯基氯化锡 在 H₂O 作用下， 以 乙醚 为溶剂， 生成 n-tetradecyltriphenylstannane
  参考文献：
  名称：

  Structural relationships in the homologous series of alkyltriphenylstannane compounds of formula Ph3Sn(CH2)n−1CH3, with n even and in the range 4–14 and 18

  摘要：

  The solid state structures of several compounds in the homologous series of alkyltriphenylstannanes of general formula Ph3Sn(CH2)(n-1)CH3 have been determined. For it in the range 4-10 the structures are monoclinic with space group P21/c. For n greater than 10 they are, instead, triclinic with space group P (1) over bar. The structural difference between the two classes is attributable to a change in the degree of control over the packing of the molecules exerted by the triphenylstannyl entity on the one hand and the alkyl chain on the other. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.07.024

文献信息

• Structural relationships in the homologous series of alkyltriphenylstannane compounds of formula Ph3Sn(CH2)n−1CH3, with n even and in the range 4–14 and 18
  作者：Gillian M. Allan、R. Alan Howie、John N. Low、Janet M.S. Skakle、James L. Wardell、Solange M.S.V. Wardell

  DOI：10.1016/j.poly.2005.07.024

  日期：2006.2

  The solid state structures of several compounds in the homologous series of alkyltriphenylstannanes of general formula Ph3Sn(CH2)(n-1)CH3 have been determined. For it in the range 4-10 the structures are monoclinic with space group P21/c. For n greater than 10 they are, instead, triclinic with space group P (1) over bar. The structural difference between the two classes is attributable to a change in the degree of control over the packing of the molecules exerted by the triphenylstannyl entity on the one hand and the alkyl chain on the other. (c) 2005 Elsevier Ltd. All rights reserved.
• Synthesis and crystal structure of bis{di-μ-hydroxobis[fac-tribromoaquotin(IV)]} heptahydrate
  作者：R. Alan Howie、Janet M. S. Skakle、James L. Wardell

  DOI：10.1016/j.ica.2005.04.035

  日期：2005.7

  Sn(O2H)Br3] · 7H2O, 2[fac-(1: X = Br)] · 7H2O. Previous reports had indicated that the tin complexes, [fac-(1: X = Cl or Br)], had been obtained in various solvated forms from hydrolysis or oxidation/hydrolysis of appropriate tin(IV) or tin(II) halides. The crystal structure determination, reported here, provides an improved refinement of the core, i.e., [fac-(1: X = Br)], of 2[fac-(1: X = Br)] · 7H2O compared

  摘要从Br2和Ph3 Sn（CH2）13CH3在空气中的CHCl3溶液中以3：1的摩尔比反应混合物中分离出的产物是双di-μ-羟基双（fac-tribromoaquotin（IV）]}七水合物，[ Br3（H2O）Sn（μ-OH）2 Sn（O2H）Br3]·7H2O，2 [fac-（1：X = Br）]·7H2O。先前的报道表明，锡配合物[fac-（1：X = Cl或Br）]是通过适当的锡（IV）或锡（II）卤化物的水解或氧化/水解而以各种溶剂化形式获得的。与以前的尝试相比，此处报道的晶体结构确定提供了2 [fac-（1：X = Br）]·7H2O改进的核细度，即[fac-（1：X = Br）]·7H2O。固态结构由中心菱形平面Sn2O2环组成。锡中心具有扭曲的八面体几何形状，每个Br配体都转变为O原子。Br配体转化为aqua配体，