| 950773-71-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• CAS: 950773-71-4
• 化学式: C₂₇H₃₀O₃Si
• 分子量: 430.619
• InChiKey: KVYKZTXATFGQHB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.19
• 重原子数：
  31.0
• 可旋转键数：
  3.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  60.69
• 氢给体数：
  3.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  在 四丁基氟化铵 作用下， 以 四氢呋喃 为溶剂， 反应 9.0h， 以100%的产率得到3,3,3-tris(3-hydroxyphenyl)propyne
  参考文献：
  名称：

  Synthesis of a Triply-Bridged Molecular Gyroscope by a Directed Meridional Cyclization Strategy

  摘要：

  A crystalline triply bridged molecular gyroscope has been prepared and analyzed by single-crystal X-ray diffraction. A convergent synthetic strategy was developed to control the direction of the three bridges, from the preferred two zonal and one meridional arrangement of a one-step cylclization process to the directed three meridional bridges achieved by a north-south desymmetrization.

  DOI：

  10.1021/ol071379y
• 作为产物：
  描述：

  在 三溴化硼 作用下， 以 二氯甲烷 为溶剂， 反应 5.0h， 以92%的产率得到
  参考文献：
  名称：

  Synthesis of a Triply-Bridged Molecular Gyroscope by a Directed Meridional Cyclization Strategy

  摘要：

  A crystalline triply bridged molecular gyroscope has been prepared and analyzed by single-crystal X-ray diffraction. A convergent synthetic strategy was developed to control the direction of the three bridges, from the preferred two zonal and one meridional arrangement of a one-step cylclization process to the directed three meridional bridges achieved by a north-south desymmetrization.

  DOI：

  10.1021/ol071379y