endo-Bicyclo<2.2.1>hepten-5-dicarbonsaeure-2,3-N-hexyl-imid | 46865-85-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: endo-Bicyclo<2.2.1>hepten-5-dicarbonsaeure-2,3-N-hexyl-imid
• 英文别名: N-hexyl-endo-norbornene-5,6-dicarboximide；2-hexyl-(3ac,7ac)-3a,4,7,7a-tetrahydro-4r,7c-methano-isoindole-1,3-dione；2-Hexyl-(3ac,7ac)-3a,4,7,7a-tetrahydro-4r,7c-methano-isoindol-1,3-dion
• CAS: 46865-85-4
• 化学式: C₁₅H₂₁NO₂
• 分子量: 247.337
• InChiKey: GXRFVEYCFZPJDT-MPZDIEGVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.37
• 重原子数：
  18.0
• 可旋转键数：
  5.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  37.38
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  正己胺 、 3,6-endomethylene-1,2,3,6-tetrahydrophthalic anhydride 以 甲苯 为溶剂， 以73%的产率得到endo-Bicyclo<2.2.1>hepten-5-dicarbonsaeure-2,3-N-hexyl-imid
  参考文献：
  名称：

  Degradable precision polynorbornenes via ring-opening metathesis polymerization

  摘要：

  ABSTRACTIn an attempt to introduce monomer sequence control in a growing polynorbornene via ring‐opening metathesis polymerization, we employ dioxepins to efficiently determine the location of the monomers on the macromolecule backbone. Owing to the acid‐labile acetal group, dioxepins allow scission of the polymer at the point of the dioxepin insertion and thus provide an indirect way to determine the monomer location. Additionally, dioxepins are used as spacers in the synthesis of multiblock polynorbornenes that are readily cleavable to afford the individual polynorbornene blocks. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016, 54, 1236–1242

  DOI：

  10.1002/pola.27964

文献信息

• N-ALKYL IMIDES AND THEIR REDUCTION BY MEANS OF LITHIUM ALUMINUM HYDRIDE
  作者：LEONARD M. RICE、E. EMMET REID、CHARLES H. GROGAN

  DOI：10.1021/jo01371a002

  日期：1954.6