N-tert-butyl-O-[1-(4-(mercaptomethyl)phenyl)ethyl]-N-(2-methyl-1-phenylpropyl)hydroxylamine | 1100759-27-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-tert-butyl-O-[1-(4-(mercaptomethyl)phenyl)ethyl]-N-(2-methyl-1-phenylpropyl)hydroxylamine
• CAS: 1100759-27-0
• 化学式: C₂₃H₃₃NOS
• 分子量: 371.587
• InChiKey: HUIDJQQNUWFDSP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.61
• 重原子数：
  26.0
• 可旋转键数：
  7.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  12.47
• 氢给体数：
  1.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  4-(乙烯基)苯基甲硫醇 在 sodium tetrahydroborate 、 2,2′-((1E,1′E)-(ethane-1,2-diylbis(azanylylidene))bis(methanylylidene))diphenolmanganese(II) 、 1,4-dithio-D,L-threitol 、 sodium hydroxide 作用下， 以 乙醇 、 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 生成 N-tert-butyl-O-[1-(4-(mercaptomethyl)phenyl)ethyl]-N-(2-methyl-1-phenylpropyl)hydroxylamine
  参考文献：
  名称：

  Reversible crosslinking of polymers bearing pendant or terminal thiol groups prepared by nitroxide-mediated radical polymerization

  摘要：

  Monomers or N-alkoxyamine initiators containing protected thiol groups are utilized to prepare polymers via nitroxide-mediated radical polymerization. Following thiol deprotection, the macromolecular properties of these polymers are manipulated, by adjusting the redox conditions to either form or cleave disulfide bonds, or irreversibly cap free thiols by the rapid addition to a maleimide Michael acceptor. Formation of disulfide bonds under dilute conditions results in intramolecular disulfide formation, resulting in internal polymer collapse. Alternatively, disulfide formation under high concentration results in intermolecular crosslinking of polymers to form networked macromolecular assemblies. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.reactfunctpolym.2013.01.009