bis(o-carboxyphenylaminomethyl)ferrocenylmethylphosphine | 495381-48-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(o-carboxyphenylaminomethyl)ferrocenylmethylphosphine
• 英文别名: 2-[[(2-carboxyanilino)methyl-(cyclopenta-2,4-dien-1-ylmethyl)phosphanyl]methylamino]benzoic acid;cyclopenta-1,3-diene;iron(2+)
• CAS: 495381-48-1
• 化学式: C₂₇H₂₇FeN₂O₄P
• 分子量: 530.343
• InChiKey: JDMJZLGJYSVARE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  (ferrocenylmethyl)bis(hydroxymethyl)phosphine 、 邻氨基苯甲酸 以 甲醇 为溶剂， 以72%的产率得到bis(o-carboxyphenylaminomethyl)ferrocenylmethylphosphine
  参考文献：
  名称：

  Water-soluble aminomethyl(ferrocenylmethyl)phosphines and their trinuclear transition metal complexes

  摘要：

  Reactions of bis(hydroxymethyl)ferrocenylmethylphosphine (1) with amino acids (o-aminobenzoic acid, potassium glycinate and 5-aminoisophthalic acid) lead to the metal-containing phosphino amino acids 1,3-bis(carboxymethyl)-5-(ferrocenylmethyl)-1,3diaza-5-phosphacyclohexane (2), bis(o-carboxyphenylaminomethyl)ferrocenylmethylphosphine (3), and 1,5-bis(meta-dicarboxyphenyl)-3,7-bis(ferrocenylmethyl)-1,5-diaza-3,7-diphosphacyclooctane (4), respectively. Water-soluble trinuclear complexes 5 and 6 were obtained by complexation of 4 with [MCl2(cod)] (M = Pt, Pd; cod = cyclooctadiene) in DMF. Compounds 1-6 were characterized by multinuclear NMR and IR spectroscopy and microanalysis. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(02)01168-3