A Convenient Method for the Synthesis of Diacyl Disulfides
摘要:
A simple and general method for the synthesis of diacyl disulfides is reported. Sulfur is allowed to react with sodium hydroxide to give sodium disulfide at 65 degrees C under PTC, which can react with acyl halides to afford diacyl disulfides in good to excellent isolated yields. The effects of solvents and phase transfer catalysts are discussed.
The present invention relates to curable compositions based on elemental sulfur and polymer components. The inventive composition cures in the presence of elemental sulfur, thus providing a novel composition with enhanced chemical and physical properties in particular useful for sealing and coating applications.
[EN] SULFUR-BASED POLYMERS<br/>[FR] POLYMÈRES À BASE DE SOUFRE
申请人:CONSTR RES & TECH GMBH
公开号:WO2015107002A1
公开(公告)日:2015-07-23
The present invention relates to curable compositions based on elemental sulfur and polymer components. The inventive composition cures in the presence of elemental sulfur, thus providing a novel composition with enhanced chemical and physical properties in particular useful for sealing and coating applications.
A Convenient Method for the Synthesis of Diacyl Disulfides
A simple and general method for the synthesis of diacyl disulfides is reported. Sulfur is allowed to react with sodium hydroxide to give sodium disulfide at 65 degrees C under PTC, which can react with acyl halides to afford diacyl disulfides in good to excellent isolated yields. The effects of solvents and phase transfer catalysts are discussed.