| 136710-89-9

• 分子结构分类: 有机化合物
• CAS: 136710-89-9
• 化学式: C₅₄H₃₂CdN₄
• 分子量: 849.285
• InChiKey: OYQBZSJNOOTTLB-MNZMCYINSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  氧气 、 在 氧气 作用下， 以 1,4-二氧六环 、 吡啶 为溶剂， 生成 oxygen
  参考文献：
  名称：

  Singlet oxygen generation by tetrabenzoporphyrins as photosensitizer

  摘要：

  The efficiency of the photosensitized generation of singlet oxygen (O-1(2)) with meso-phenyl substituted tetrabenzoporphyrin metallo complexes as sensitizer was determined from the limiting quantum yield of the (+)-limonene photooxygenation and compared with that of hematoporphyrin (HP), which has been known to serve as an effective sensitizer, using a He-Ne laser light (633 mm). Among the diamagnetic (Mg, Zn, and Cd) complexes treated here, the Zn complexes were most efficient for the (+)-limonene photooxygenation with the limiting quantum yields of PHI(-A) = 0.4. This result was comparable to that of HP. The direct observation of the intensity of O-1(2) emission by the laser flash photolysis technique supported these results.

  DOI：

  10.1016/s0020-1693(00)85070-7
• 作为产物：
  描述：

  meso-diphenyltetrabenzoporphyrin zinc 、 cadmium(II) acetate 、 三氟乙酸 以 氯仿 为溶剂， 生成
  参考文献：
  名称：

  Singlet oxygen generation by tetrabenzoporphyrins as photosensitizer

  摘要：

  The efficiency of the photosensitized generation of singlet oxygen (O-1(2)) with meso-phenyl substituted tetrabenzoporphyrin metallo complexes as sensitizer was determined from the limiting quantum yield of the (+)-limonene photooxygenation and compared with that of hematoporphyrin (HP), which has been known to serve as an effective sensitizer, using a He-Ne laser light (633 mm). Among the diamagnetic (Mg, Zn, and Cd) complexes treated here, the Zn complexes were most efficient for the (+)-limonene photooxygenation with the limiting quantum yields of PHI(-A) = 0.4. This result was comparable to that of HP. The direct observation of the intensity of O-1(2) emission by the laser flash photolysis technique supported these results.

  DOI：

  10.1016/s0020-1693(00)85070-7