| 1507367-14-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1507367-14-7
• 化学式: C₄₉H₅₅I₂N₂P₂Sb
• 分子量: 1109.5
• InChiKey: KWEYBJZQTFQAMZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  K[HC(Ph2PNdipp)2] 、 碘化锑 以 四氢呋喃 、 甲苯 为溶剂， 生成
  参考文献：
  名称：

  Heavy Group 15 Element Compounds of a Sterically Demanding Bis(iminophosphorane)methanide and -methanediide

  摘要：

  Complexes of the heavy pnictogen elements Sb and Bi of monoanionic (C,N-chelated: Sb, Bi) and dianionic (N,C,N-pincer type: Bi) bulky substituted bis(diphenyl-(arylimino)phosphorano)methane H2C(Ph2PNR)(2) (R = 2,6-diisopropylphenyl (dipp)) have been prepared via metathetical reactions, and tautomerism within the monoanionic ligand backbone has been observed. The complexes have been characterized by means of X-ray analysis and NMR studies. The dianionic complex was found to feature the rare structural motif of a formal carbon-bismuth(III) double bond. The molecular structure of the solvate-free potassium salt K[HC(Ph(2)PNdipp)(2)] is reported.

  DOI：

  10.1021/om401059x