Bis-trichloracetyl-hydrochinon | 7027-00-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: Bis-trichloracetyl-hydrochinon
• 英文别名: p-Hydrochinon-bis(trichloracetat)；1,4-bis-trichloroacetoxy-benzene；1,4-Bis-trichloracetoxy-benzol；Bis-O-trichloracetyl-hydrochinon；[4-(2,2,2-Trichloroacetyl)oxyphenyl] 2,2,2-trichloroacetate
• CAS: 7027-00-1
• 化学式: C₁₀H₄Cl₆O₄
• 分子量: 400.857
• InChiKey: YBVOLUVCKKJMMK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  三氯乙酰氯 、 alkaline earth salt of/the/ methylsulfuric acid 在 Petroleum ether 作用下， 生成 Bis-trichloracetyl-hydrochinon
  参考文献：
  名称：

  Sen; Bhargava, Journal of the Indian Chemical Society, 1949, vol. 26, p. 243

  摘要：

  DOI：

文献信息

• METHOD FOR PREPARING HALOGENATED ORGANOPHOSPHINES
  申请人：Zavorine Serguei I.

  公开号：US20110071319A1

  公开（公告）日：2011-03-24

  The present application relates to a process for preparing a halogenated organophosphine, comprising reacting a primary or secondary organophosphine with a halogenating agent selected from (A) a compound of formula (I): (HaI) 3 C—C(O)—X (I) wherein X is selected from alkyl, aryl, aralkyl, alkaryl, cycloalkyl, NR 1 R 2 , C(HaI) 3 , OR 3 , -0—C(O)—R 3′ , or —Y—Z—Y—C(O)—C(HaI) 3 ; R1 and R2 are each independently selected from hydrogen, alkyl, aryl, aralkyl, alkaryl, or cycloalkyl; R3 is selected from H, alkyl, aryl, aralkyl, alkaryl, cycloalkyl, or triorganosilyl; R 3′ is selected from C(HaI) 3 , alkyl, aryl, aralkyl, alkaryl, cycloalkyl; Y is independently selected from 0 or NH; Z is independently selected from alkylene, arylene, aralkylene, alkarylene, or cycloakylene; and Hal is selected from Cl or Br; or (B) a derivative of a polyol, polyamine or polyaminoalcohol comprising two or more hydroxyl and/or amino groups, in which a hydrogen atom in each of the hydroxyl and/or amino groups is replaced with a group —C(O)—C(HaI) 3 , wherein Hal is selected from Cl or Br.

  本申请涉及一种制备卤代有机膦的方法，包括将一种一级或二级有机膦与一种卤化试剂反应，所述卤化试剂选自以下组合物：（A）式（I）的化合物：（HaI）3C—C（O）—X（I），其中X选自烷基、芳基、芳基烷基、烷芳基、环烷基、NR1R2、C（HaI）3、OR3、-0—C（O）—R3'或—Y—Z—Y—C（HaI）3；R1和R2各自独立地选自氢、烷基、芳基、芳基烷基、烷芳基或环烷基；R3选自H、烷基、芳基、芳基烷基、烷芳基、环烷基或三有机硅基；R3'选自C（HaI）3、烷基、芳基、芳基烷基、烷芳基或环烷基；Y各自独立地选自0或NH；Z各自独立地选自烷基、芳基、芳基烷基、烷芳基或环烷基；Hal选自Cl或Br；或（B）一种多元醇、多胺或多胺醇的衍生物，其中包含两个或两个以上的羟基和/或氨基团，其中每个羟基和/或氨基团中的一个氢原子被一个基团—C（O）—C（HaI）3所取代，其中Hal选自Cl或Br。
• 111. The electric polarisation of mercurous trichloroacetate and of quinol bistrichloroacetate
  作者：N. R. Davidson、L. E. Sutton

  DOI：10.1039/jr9420000565

  日期：——
• [EN] METHOD FOR PREPARING HALOGENATED ORGANOPHOSPHINES<br/>[FR] PROCÉDÉ POUR LA FABRICATION D'ORGANOPHOSPHINES HALOGÉNÉES
  申请人：CYTEC CANADA INC

  公开号：WO2009147495A2

  公开（公告）日：2009-12-10

  The present application relates to a process for preparing a halogenated organophosphine, comprising reacting a primary or secondary organophosphine with a halogenating agent selected from (A) a compound of formula (I) : (HaI)3C-C(O)-X (I) wherein X is selected from alkyl, aryl, aralkyl, alkaryl, cycloalkyl, NR1R2, C(HaI)3, OR3, -0-C(O)-R3', or -Y-Z-Y-C(O)- C(HaI)3; R1 and R2 are each independently selected from hydrogen, alkyl, aryl, aralkyl, alkaryl, or cycloalkyl; R3 is selected from H, alkyl, aryl, aralkyl, alkaryl, cycloalkyl, or triorganosilyl; R3' is selected from C(HaI)3, alkyl, aryl, aralkyl, alkaryl, cycloalkyl; Y is independently selected from 0 or NH; Z is independently selected from alkylene, arylene, aralkylene, alkarylene, or cycloakylene; and Hal is selected from Cl or Br; or (B) a derivative of a polyol, polyamine or polyaminoalcohol comprising two or more hydroxyl and/or amino groups, in which a hydrogen atom in each of the hydroxyl and/or amino groups is replaced with a group -C(O)-C(HaI)3, wherein Hal is selected from Cl or Br.
• Sen; Bhargava, Journal of the Indian Chemical Society, 1949, vol. 26, p. 243
  作者：Sen、Bhargava

  DOI：——

  日期：——