trans-bis(4-methylbenzohydrazide-κ2-N',O)copper(II)sulfate | 51997-08-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans-bis(4-methylbenzohydrazide-κ2-N',O)copper(II)sulfate
• 英文别名: copper;4-methylbenzohydrazide;sulfate
• CAS: 51997-08-1；449165-15-5
• 化学式: C₁₆H₂₀CuN₄O₂*O₄S
• 分子量: 459.97
• InChiKey: ZCLNGOIHBCPZEG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(ll) sulfate pentahydrate 、 对甲苯甲酰肼 以 甲醇 、 水 为溶剂， 以68%的产率得到trans-bis(4-methylbenzohydrazide-κ2-N',O)copper(II)sulfate
  参考文献：
  名称：

  SYNTHESIS AND STRUCTURAL FEATURES OF COPPER(II) COMPLEXES OF BENZOIC ACID AND METHYL SUBSTITUTED BENZOIC ACID HYDRAZIDES AND X-RAY STRUCTURE OF Cu[C₆H₅CONHNH₂]₂(NO₃)₂

  摘要：

  The synthesis, spectroscopic, magnetic and biological activities of copper(II) complexes of benzoic acid hydrazides (BAH) and o, m, and p-substituted methylbenzoic acid hydrazides (MBAH) and the single crystal X-ray structure for bis(benzoic acid hydrazide)copper(II) nitrate {Cu[BAH](2)(NO3)(2)} (BAH = Benzoic acid hydrazide) are reported. The composition of the ligands was established by elemental analyses, H-1 NMR, and GC-MS. Magnetic susceptibility, electronic and infrared spectral data are consistent with a mononuclear square-planar geometry with bidentate coordination of the hydrazide ligands to give essentially a CUN2O2 chromophore. Cu[BAH](2)(NO3)(2) crystallizes from methanol solution under ambient temperature in a monoclinic system with a P2(1)/c space system. The copper atom has a nearly regular, four-coordinated, square-planar arrangement with the nitrate anions being uncoordinated in the crystal lattice. The compounds did not show significant activity against selected bacteria and fungi.

  DOI：

  10.1081/sim-120004447