[Nb(Me2Si(η5-C5Me4)(η5-C5H4))Cl2] | 470665-78-2

• 英文名称: [Nb(Me2Si(η5-C5Me4)(η5-C5H4))Cl2]
• CAS: 470665-78-2
• 化学式: C₁₆H₂₂Cl₂NbSi
• 分子量: 406.249
• InChiKey: JZBXRQXEPVUVRW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Nb(Me2Si(η5-C5Me4)(η5-C5H4))Cl2] 、 二苯基乙炔 在 sodium amalgam 作用下， 以 四氢呋喃 为溶剂， 以80%的产率得到[Nb(Me2Si(η5-C5Me4)(η5-C5H4))Cl(PhCCPh)]
  参考文献：
  名称：

  Synthesis and electrochemistry of niobium complexes incorporating asymmetrically substituted ansa-ligands

  摘要：

  The following asymmetric ansa-niobocene(IV) dichloride complexes have been prepared: [Nb{Me2Si(eta(5)-C5Me4)(eta(5)-C5H3R)}Cl-2] (R = H (1a), Me (2a), SiMe3 (3a), Pr-i (4a), PPh2 (5a)). The ESR spectra of 1a-5a have been recorded. Oxidation and reduction potentials have also been measured and compared with nonansa-niobocene complexes. The new niobocene complexes [Nb(eta(5)-C5H4R)(2)}Cl-2] ;(R = Pr-i (6a), PPh2 (7a)) have been also synthesized. In addition, reduction of 1a in the presence of ligand (RCdropCR) (R=Me, Ph) to give [Nb{Me2Si(eta(5)-C5Me4)(eta(5)-C5H4)}Cl(RCdropCR)] (R=Me (8a), Ph (9a)) is described. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01414-6
• 作为产物：
  描述：

  四氯双(四氢呋喃)合铌(IV) 、 以 四氢呋喃 为溶剂， 以73%的产率得到[Nb(Me2Si(η5-C5Me4)(η5-C5H4))Cl2]
  参考文献：
  名称：

  Synthesis and electrochemistry of niobium complexes incorporating asymmetrically substituted ansa-ligands

  摘要：

  The following asymmetric ansa-niobocene(IV) dichloride complexes have been prepared: [Nb{Me2Si(eta(5)-C5Me4)(eta(5)-C5H3R)}Cl-2] (R = H (1a), Me (2a), SiMe3 (3a), Pr-i (4a), PPh2 (5a)). The ESR spectra of 1a-5a have been recorded. Oxidation and reduction potentials have also been measured and compared with nonansa-niobocene complexes. The new niobocene complexes [Nb(eta(5)-C5H4R)(2)}Cl-2] ;(R = Pr-i (6a), PPh2 (7a)) have been also synthesized. In addition, reduction of 1a in the presence of ligand (RCdropCR) (R=Me, Ph) to give [Nb{Me2Si(eta(5)-C5Me4)(eta(5)-C5H4)}Cl(RCdropCR)] (R=Me (8a), Ph (9a)) is described. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01414-6