N,N'-bis(3,5-dichlorophenyl)-2-methyl-2-pyridin-2-ylpropane-1,3-diamine | 391879-64-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-bis(3,5-dichlorophenyl)-2-methyl-2-pyridin-2-ylpropane-1,3-diamine
• CAS: 391879-64-4
• 化学式: C₂₁H₁₉Cl₄N₃
• 分子量: 455.214
• InChiKey: APBZMMQBWKTAPJ-UHFFFAOYSA-N

物化性质

• 沸点：
  631.0±55.0 °C(Predicted)
• 密度：
  1.401±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  28
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  37
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  tetrachlorobis(tetrahydrofurano)molybdenum(IV) 、 N,N'-bis(3,5-dichlorophenyl)-2-methyl-2-pyridin-2-ylpropane-1,3-diamine 、 三乙胺 以 四氢呋喃 为溶剂， 以78%的产率得到
  参考文献：
  名称：

  Synthesis of Molybdenum and Tantalum Complexes that Contain Diamido/Donor Ligands of the Type [(3,5-Cl₂C₆H₃NCH₂CH₂)₂NMe]^2- or [(3,5-Cl₂C₆H₃NCH₂)₂C(2-C₅H₄N)(CH₃)]^2-

  摘要：

  The palladium-catalyzed reaction between diethylenetriamine and 2 equiv of 3,5-dichlorobromobenzene gave (3,5-Cl2C6H3NHCH2CH2)(2)NH. Methylation of the central nitrogen with methyl iodide gave (3,5-Cl2C6H3NHCH2CH2)(2)NMe (H-2[ArClNNMe]). The palladium-catalyzed reaction between (H2NCH2)(2)C(2-C5H4N)(CH3) and 3,5-dichlorobromobenzene gave (3,5-Cl2C6H3HNCH2)(2)C(2-C5H4N)(CH3) (H-2[Ar(Cl)Npy]). Molybdenum compounds that were prepared include [Et3NH]{[ArClNNMe]MOCl3} (1a), (ArClNNMe]Mo(CCMe3)(CH2CMe3) (2), [ArClNNMe]MoCl(CH2R) [R = CMe3 (4a) or SiMe3 (4b)], [Et3NH]{[Ar(Cl)Npy]MoCl3} (5), and Mo[Ar(Cl)Npy](2) (6). Tantalum complexes that were prepared include [ArClNNMe]TaMe3 (7) and (Ar(Cl)Npy]TaMe3 (8). X-ray studies of 1a, 4a, 6, and 7 are reported.

  DOI：

  10.1021/om0106985