| 51329-43-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 51329-43-2
• 化学式: C₂₈H₁₆Cl₄Mo₂O₈
• 分子量: 814.122
• InChiKey: NHXCHBYROQKDRH-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  tetrapotassium octachlorodimolybdate(II) 、 2-氯苯甲酸 以 甲醇 、 水 为溶剂， 以85.6%的产率得到
  参考文献：
  名称：

  The effects, assessed by electrochemical techniques and single crystal structures, of ortho substitution on benzoate ligands supporting the quadruply-bonded dimolybdenum bond

  摘要：

  The syntheses, electrochemistry and structures of Mo-2(O2C-o-C6H4Cl)(4), 1(.)4THF, Mo-2(O2C-o-C6H4Br)(4), 2(.)2THF, Mo-2(O2C-o-C6H4I)(4), 3(.)2THF, and Mo-2(O2C-o-C6H4NO2)(4) (4), as determined by single-crystal X-ray diffraction, are reported. Molecules 1, 2, and 3 co-crystallized each with two axially coordinated THF molecules; complex 1 contained two more THF molecules within the unit cell. The Mo-Mo distances in 1-4 are 2.1029(10), 2.1014(13), 2.1055(7), and 2.0942(12) Angstrom, respectively. The oxidation potentials for 1-3 were similar at 674, 655, and 647 mV, but that for 4 at an E-1/2(ox) of 792 mV was higher. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01095-2