N-[4-[(Trifluoromethyl)sulfonylaminosulfonyl]phenyl]methacrylamide | 744215-90-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-[4-[(Trifluoromethyl)sulfonylaminosulfonyl]phenyl]methacrylamide
• 英文别名: 2-methyl-N-[4-(trifluoromethylsulfonylsulfamoyl)phenyl]prop-2-enamide
• CAS: 744215-90-5
• 化学式: C₁₁H₁₁F₃N₂O₅S₂
• 分子量: 372.346
• InChiKey: LUNSFNCWXNNFIC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  23
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  126
• 氢给体数：
  2
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  磺胺 在 N-苯基-2-萘胺 、 potassium carbonate 作用下， 以 丙酮 为溶剂， 反应 3.5h， 生成 N-[4-[(Trifluoromethyl)sulfonylaminosulfonyl]phenyl]methacrylamide
  参考文献：
  名称：

  一系列基于磺酰亚胺的新型质子传导膜酸性单体的合成，表征和共聚

  摘要：

  描述了基于具有不同酸度的磺酰亚胺的一系列新型酸单体的合成和表征。进行酸单体与丙烯腈的共聚，并从所得共聚物的溶液流延质子交换膜。可以制备具有不同当量的柔性，机械强度高且透明的膜。与较低的当量重量和较低的酸度相比，较低的当量重量和较高的酸度的膜在加湿条件下表现出较高的质子传导性。膜电极组件是使用合成的磺酰亚胺共聚物制造的。H 2 / O 2 在单个电池中测试了燃料电池的性能，这揭示了磺酰亚胺膜对聚合物电解质燃料电池的潜在适用性。

  DOI：

  10.1021/ma0498058

文献信息

• Near infrared absorbing colorant polymer, composition, film, optical filter, pattern forming method, and device
  申请人：FUJIFILM Corporation

  公开号：US10711082B2

  公开（公告）日：2020-07-14

  A near infrared absorbing colorant polymer has a maximal absorption in a wavelength range of 700 to 1200 nm. It is preferable that the near infrared absorbing colorant polymer includes at least one near infrared absorbing colorant structure selected from the group consisting of a pyrrolopyrrole colorant, a cyanine colorant, a squarylium colorant, a diimonium colorant, a phthalocyanine colorant, a naphthalocyanine colorant, a rylene colorant, a dithiol complex colorant, a croconium colorant, an oxonol colorant, a triarylmethane colorant, a pyrromethene colorant, an azomethine colorant, an anthraquinone colorant, and a dibenzofuranone colorant.

  近红外吸收着色剂聚合物的最大吸收波长范围为 700 至 1200 纳米。酞菁着色剂、萘酞菁着色剂、烯着色剂、二硫醇络合物着色剂、巴豆着色剂、羰基醇着色剂、三芳基甲烷着色剂、吡咯烷酮着色剂、偶氮甲烷着色剂、蒽醌着色剂和二苯并呋喃酮着色剂。
• NEAR INFRARED ABSORBING COLORANT POLYMER, COMPOSITION, FILM, OPTICAL FILTER, PATTERN FORMING METHOD, AND DEVICE
  申请人：FUJIFILM Corporation

  公开号：US20180118865A1

  公开（公告）日：2018-05-03

  A near infrared absorbing colorant polymer has a maximal absorption in a wavelength range of 700 to 1200 nm. It is preferable that the near infrared absorbing colorant polymer includes at least one near infrared absorbing colorant structure selected from the group consisting of a pyrrolopyrrole colorant, a cyanine colorant, a squarylium colorant, a diimonium colorant, a phthalocyanine colorant, a naphthalocyanine colorant, a rylene colorant, a dithiol complex colorant, a croconium colorant, an oxonol colorant, a triarylmethane colorant, a pyrromethene colorant, an azomethine colorant, an anthraquinone colorant, and a dibenzofuranone colorant.
• Synthesis, Characterization, and Copolymerization of a Series of Novel Acid Monomers Based on Sulfonimides for Proton Conducting Membranes
  作者：Md. Khalilur Rahman、Gentaro Aiba、Md. Abu Bin Hasan Susan、Yuko Sasaya、Ken-ichiro Ota、Masayoshi Watanabe

  DOI：10.1021/ma0498058

  日期：2004.7.1

  The synthesis and characterization of a series of novel acid monomers based on sulfonimides with different acidities are described. Copolymerization of the acid monomers with acrylonitrile was carried out, and the proton exchange membranes were cast from solutions of the resulting copolymers. Flexible, mechanically strong, and transparent membranes with different equivalent weights could be prepared

  描述了基于具有不同酸度的磺酰亚胺的一系列新型酸单体的合成和表征。进行酸单体与丙烯腈的共聚，并从所得共聚物的溶液流延质子交换膜。可以制备具有不同当量的柔性，机械强度高且透明的膜。与较低的当量重量和较低的酸度相比，较低的当量重量和较高的酸度的膜在加湿条件下表现出较高的质子传导性。膜电极组件是使用合成的磺酰亚胺共聚物制造的。H 2 / O 2 在单个电池中测试了燃料电池的性能，这揭示了磺酰亚胺膜对聚合物电解质燃料电池的潜在适用性。