gold(III)(pentafluorophenyl)3(P(phenyl)2H) complex | 219638-47-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: gold(III)(pentafluorophenyl)3(P(phenyl)2H) complex
• 英文别名: diphenylphosphane;gold(3+);1,2,3,4,5-pentafluorobenzene-6-ide
• CAS: 219638-47-8
• 化学式: C₃₀H₁₁AuF₁₅P
• 分子量: 884.334
• InChiKey: UKTVMXHHPQTLEZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(triphenylphosphine)iminium gold(I) bis(acetylide) 、 gold(III)(pentafluorophenyl)3(P(phenyl)2H) complex 以 二氯甲烷 为溶剂， 以90%的产率得到[N(P(C6H5)3)2][(gold(III)(pentafluorophenyl)3(μ-P(C6H5)2))2gold(I)]
  参考文献：
  名称：

  [Au(C6F5)3(PPh2H)]: A Precursor for the Synthesis of Gold(III) Phosphide Complexes

  摘要：

  The covalent radius of AuI is about 0.07 Å smaller than that of AgI . This was determined from the crystal structures of the isostructural complexes [N(PPh3 )][{Au(C6 F5 )3 (μ-PPh2 )}2 M] (M=Au (structure shown in the picture), Ag). These mixed AuIII -M phosphides were synthesized from [Au(C6 F5 )3 (PPh2 H)], the first gold complex to contain a secondary phosphane.

  DOI：

  10.1002/(sici)1521-3773(19981116)37:21<3042::aid-anie3042>3.0.co;2-c
• 作为产物：
  描述：

  tris(pentafluorophenyl)(tetrahydrothiophene)gold(III) 、 二苯基膦 以 乙醚 为溶剂， 以37%的产率得到gold(III)(pentafluorophenyl)3(P(phenyl)2H) complex
  参考文献：
  名称：

  [Au(C6F5)3(PPh2H)]: A Precursor for the Synthesis of Gold(III) Phosphide Complexes

  摘要：

  The covalent radius of AuI is about 0.07 Å smaller than that of AgI . This was determined from the crystal structures of the isostructural complexes [N(PPh3 )][{Au(C6 F5 )3 (μ-PPh2 )}2 M] (M=Au (structure shown in the picture), Ag). These mixed AuIII -M phosphides were synthesized from [Au(C6 F5 )3 (PPh2 H)], the first gold complex to contain a secondary phosphane.

  DOI：

  10.1002/(sici)1521-3773(19981116)37:21<3042::aid-anie3042>3.0.co;2-c