7,7,9,9-tetramethyl-3-(2,3-epoxypropyl)-1,3,8-triazaspiro[4.5]decane-2,4-dione | 40327-12-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑烷类
• 英文名称: 7,7,9,9-tetramethyl-3-(2,3-epoxypropyl)-1,3,8-triazaspiro[4.5]decane-2,4-dione
• 英文别名: 7,7,9,9-tetramethyl-3-(2,3-epoxypropyl)-2,4-dioxo-1,3,8-triazaspiro[4.5]decane；7,7,9,9-tetramethyl-3-oxiranylmethyl-1,3,8-triaza-spiro[4.5]decane-2,4-dione；1,3,8-triaza-3-(2,3-epoxypropyl)-7,7,9,9-tetramethyl-spiro[4.5]decane-2,4-dione；7,7,9,9-Tetramethyl-3-(oxiran-2-ylmethyl)-1,3,8-triazaspiro[4.5]decane-2,4-dione
• CAS: 40327-12-6
• 化学式: C₁₄H₂₃N₃O₃
• 分子量: 281.355
• InChiKey: VJRDFNSJQFERTO-UHFFFAOYSA-N

物化性质

• 密度：
  1.23±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  74
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  苄胺 、 7,7,9,9-tetramethyl-3-(2,3-epoxypropyl)-1,3,8-triazaspiro[4.5]decane-2,4-dione 在 氢氧化钾 作用下， 以 甲醇 、 氯仿 为溶剂， 生成 N,N-Bis[2-hydroxy-3-(7,7,9,9-tetramethyl-2,4-dioxo-1,3,8-triazaspiro[4.5]dec-3-yl)propyl]benzylamine
  参考文献：
  名称：

  Piperidine-spiro-hydantoin derivatives and their use as polymer

  摘要：

  描述了由一般公式(I)代表的新型哌啶-螺内酰脲衍生物以及其作为合成聚合物的光稳定剂的用途：##STR1## 这些化合物在各种合成聚合物组合物中具有改善的稳定效果，如聚烯烃，对其光和/或热诱导的恶化，加热处理或含有这些化合物的成型制品在存储期间的挥发度小，以及对水和溶剂的抗萃取性。

  公开号：

  US04219465A1

文献信息

• Biocidal N-Halamine epoxides
  申请人：Worley S.D.

  公开号：US20070015921A1

  公开（公告）日：2007-01-18

  N-halaminehydantoinyl epoxide compounds which can be used for the construction of coatings and materials which can be rendered biocidal by exposure to halogen solutions either before or after curing the coating or material are disclosed. The biocidal coatings and materials can then be used to inactivate pathogenic microorganisms such as bacteria, fungi, and yeasts, as well as virus particles, which can cause infectious diseases, and those microorganisms which cause noxious odors and unpleasant coloring such as mildew. The coatings are compatible with a variety of substrates including, but not limited to, cellulose, chitin, chitosan, synthetic fibers, cement grout, latex caulk, acrylic films, polyurethanes, plastics and paints.

  本发明揭示了可用于构建涂层和材料的N-卤胺嘧啶基环氧化合物，通过暴露于卤素溶液中，无论是在涂层或材料固化之前还是之后，这些涂层和材料可以被赋予生物杀菌性能。这些生物杀菌涂层和材料可以用于灭活病原微生物，如细菌、真菌、酵母以及病毒颗粒，这些微生物可能引起传染病，以及那些引起恶臭和不愉快变色的微生物，如霉菌。这些涂层与各种基材兼容，包括但不限于纤维素、壳聚糖、壳聚糖、合成纤维、水泥灰浆、乳胶灌缝剂、丙烯酸膜、聚氨酯、塑料和油漆。
• Polymers substituted with polyalkylpiperidine side chains, preparation and use thereof as stabilizers
  申请人：SANKYO COMPANY LIMITED

  公开号：EP0001835A2

  公开（公告）日：1979-05-16

  Polymers containing polyalkylpiperidines, preparation and use thereof as stabilizers for synthetic polymer compositions are described. In said polymers, sterically hindered polyalkylpiperidines are laterally linked to the main chain. The polymers are distinguished by an improved stabilizing effect in various synthetic polymer compositions, such as polyolefins, against light- and/or heat-induced deterioration thereof. The polyalkylpiperidine-containing polymers of the invention are hardly volatile upon heat-processing or during storage of shaped articles containing said polymers, and are resistant to extraction with solvents.

  本文介绍了含有聚烷基哌啶的聚合物，以及其作为合成聚合物组合物稳定剂的制备和使用方法。在上述聚合物中，立体受阻的聚烷基哌啶与主链横向相连。这种聚合物的显著特点是能改善各种合成聚合物组合物（如聚烯烃）的稳定效果，防止光和/或热引起的劣化。本发明的含聚烷基哌啶聚合物在热加工或储存含有上述聚合物的成型物品时几乎不挥发，并且耐溶剂萃取。
• Piperidine-spiro-hydantoin derivatives and their use as light stabilizers for synthetic polymers
  申请人：SANKYO COMPANY LIMITED

  公开号：EP0006536A1

  公开（公告）日：1980-01-09

  Novel piperidine-spiro-hydantoin derivatives represented by the general formula (I) and use thereof as light stabilizers for synthetic polymers are described: The compounds are distinguished by an improved stabilizing effect in various synthetic polymer compositions, such as polyolefins, against light- and/or heat-induced deterioration thereof, low volatility upon heat- processing or during storage of shaped articles containing the compounds, and resistance to extraction with water and solvents.

  描述了通式 (I) 所代表的新型哌啶-螺-海因衍生物及其作为合成聚合物光稳定剂的用途：该化合物的显著特点是在各种合成聚合物（如聚烯烃）组合物中具有更好的稳定效果，可防止光和/或热引起的劣化，在热加工或含有该化合物的成型物品储存期间具有低挥发性，并且耐水和溶剂萃取。
• Polymers containing polyalkylpiperidines and use thereof as stabilizers
  申请人：SANKYO COMPANY LIMITED

  公开号：EP0000769B1

  公开（公告）日：1981-08-05
• Ether auf Basis von Polyalkyl-1-oxa-diazaspirodecanen, ihre Herstellung, ihre Verwendung, sowie mit ihnen stabilisierte synthetische Polymere
  申请人：HOECHST AKTIENGESELLSCHAFT

  公开号：EP0028318B1

  公开（公告）日：1982-12-22