[((4,4'-di-tert-butyl-2,2'-pyridine)Pt)3(hexathiolatobenzene)] | 1313753-76-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [((4,4'-di-tert-butyl-2,2'-pyridine)Pt)3(hexathiolatobenzene)]
• CAS: 1313753-76-2
• 化学式: C₆₀H₇₂N₆Pt₃S₆
• 分子量: 1654.91
• InChiKey: BXVJRKLCIADCKY-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  苯六硫酚 以 not given 为溶剂， 以1%的产率得到[((4,4'-di-tert-butyl-2,2'-pyridine)Pt)3(hexathiolatobenzene)]
  参考文献：
  名称：

  Expanding Family of π-Conjugated Trinuclear Dithiolenes: The Cases of Group 8 (Ru^II) and 10 (Ni^IIand Pt^II) Metals

  摘要：

  New pi-conjugated trinuclear dithiolenes with group 8 (6, Ru-II) and 10 (7 and 8, Ni-II and Pt-II) metals were synthesized. Compounds 6 and 7 exhibited intense electronic communication through the phenylene bridge among the three dithiolene moieties during oxidation of the metalladithiolene rings, which has not been confirmed in the analogous family of group 9 metals, 1-5. Compound 8 exhibited an intense absorption band across the visible and near-IR regions, which was assigned as a charge transfer to the diimine and was red-shifted and broadened compared to the corresponding band of the mononuclear complex.

  DOI：

  10.1021/ic200766p