bis(acetylacetonato)(1-phenyl-1-iminopentane-3-onato)ruthenium(III) | 851286-46-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(acetylacetonato)(1-phenyl-1-iminopentane-3-onato)ruthenium(III)
• CAS: 851286-46-9
• 化学式: C₂₁H₂₆NO₅Ru
• 分子量: 473.511
• InChiKey: JUMDUEWXMHUWKH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  苯甲腈 在 Zn 、 HCl 作用下， 以 乙醇 、 水 为溶剂， 生成 bis(acetylacetonato)(1-phenyl-1-iminopentane-3-onato)ruthenium(III)
  参考文献：
  名称：

  Reactions of ketones with coordinated nitriles on β-diketonato ruthenium complexes leading to formation of compounds with new carbon–carbon bonds

  摘要：

  The reactions of [Ru(acac)(2)(CH3CN)(2)] with four ketones (acetone, ethyl methyl ketone, acetylacetone and monochloroacetone), and the reactions of [Ru(acac)(2)(C6H5CN)(2)] with two ketones (acetone and ethyl methyl ketone) yielded six novel compounds of beta-ketiminato ruthenium complexes: [Ru(acac)(2)(mhmk)], [Ru(acac)(2)(ehmk)], [Ru(acac)(2)(mAmk)], [Ru(acac)(2)(MClmk)], [Ru(acac)(2)(mhbk)], and [Ru(acac)(2)(ehbk)] (mhmk = 4-iminopentane-2-one mono anion, ehmk = 5-iminohexane-3-one mono anion, mAmk = 3-(1-iminoethyl)-2,4-pentanedione mono anion, mClmk = 3-chloro-4-imino-pentane-2-one mono anion, mhbk = 1-phenyl-1-iminobutane-3-one mono anion, mhbk = 1-phenyl-l-iminopentane-3-one mono anion). All the new complexes have been characterized by elemental analyses, H-1 NMR, MS and electronic spectral data. Crystal and molecular structures for the six beta-ketimine complexes have been solved by single crystal X-ray diffraction studies. A mechanism involving the attack of ketones on the coordinated nitrile has been proposed. The electrochemical redox behavior of the beta-ketimine complexes has been elucidated. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.01.005