dichloro [1,2,4,5,8,9,11,12-octaazacyclohexadecane]copper(II) | 669059-90-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑烷类
• 英文名称: dichloro [1,2,4,5,8,9,11,12-octaazacyclohexadecane]copper(II)
• 英文别名: dichlorocopper;1,2,4,5,9,10,12,13-octazacyclohexadecane
• CAS: 669059-90-9
• 化学式: C₈H₂₄Cl₂CuN₈
• 分子量: 366.784
• InChiKey: PZUDQWAETNJHTH-UHFFFAOYSA-L

物化性质

• 熔点：
  >300 °C

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  聚合甲醛 、 copper(II) choride dihydrate 、 一水合肼 、 1,3-二溴丙烷 以 甲醇 为溶剂， 以52%的产率得到dichloro [1,2,4,5,8,9,11,12-octaazacyclohexadecane]copper(II)
  参考文献：
  名称：

  Synthesis and Physico‐Chemical Studies on 14‐ and 16‐Membered Octaazamacrocyclic Complexes Derived from Hydrazine with Co(II), Ni(II), Cu(II), and Zn(II)

  摘要：

  A series of 14 and 16-membered octaazamacrocyclic complexes [(MLX2)-X-1] and [(MLX2)-X-2] [M = Co(II), Ni(II), Cu(II) and Zn(II), X = Cl or NO3] have been synthesized by a template condensation reaction of hydrazine with 1,3-dibromopropane or 1,2-dibromoethane and formaldehyde in methanol. The complexes and their overall geometry and stereochemistry have been characterized by elemental analyses, IR, H-1 NMR, EPR, UV-Visible, magnetic susceptibility and conductivity measurements. An octahedral geometry is suggested for all of the complexes where two coordination sites are occupied by Cl or NO3 and the other four sites by secondary amines. The low conductivity data suggest that the complexes are non-ionic.

  DOI：

  10.1081/sim-120025441