Zn(N,N'-disalicylidene-3,5-diaminotoluene(-2H)) | 189760-64-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Zn(N,N'-disalicylidene-3,5-diaminotoluene(-2H))
• 英文别名: Zn(dst)
• CAS: 189760-64-3
• 化学式: C₂₁H₁₆N₂O₂Zn
• 分子量: 393.76
• InChiKey: YFHXYYQGSDDOPA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Zn(N,N'-disalicylidene-3,5-diaminotoluene(-2H)) 以 neat (no solvent) 为溶剂， 生成 zinc(II) oxide
  参考文献：
  名称：

  Synthesis and spectroscopic studies of complexes of zinc(II) with N2O2 donor groups

  摘要：

  Complexes of zinc(II) with N,N'-disalicylidene-1,2-pheiiylenediamine (H(2)dsp), N,N'-disalicylidene-3,4-diaminotoluene (H(2)dst), 4-nitro-N,N'-disalicylidene-1,2-phenylenediamine (H(2)ndsp) and NAP-disalicylidene ethylenediamine (H(2)salen) have been prepared and characterized by elemental analysis, electronic, IR, H-1 NMR and thermal studies. TG studies show that all complexes decomposed in one step. Kinetic and thermodynamic parameters were computed from the thermal decomposition data. The activation energy of complexes lies 60-87 kJ mol(-1) range. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2005.07.008
• 作为产物：
  描述：

  N,N'-disalicylidene-3,4-diaminotoluene 、 zinc diacetate 以 乙醇 为溶剂， 生成 Zn(N,N'-disalicylidene-3,5-diaminotoluene(-2H))
  参考文献：
  名称：

  Synthesis and spectroscopic studies of complexes of zinc(II) with N2O2 donor groups

  摘要：

  Complexes of zinc(II) with N,N'-disalicylidene-1,2-pheiiylenediamine (H(2)dsp), N,N'-disalicylidene-3,4-diaminotoluene (H(2)dst), 4-nitro-N,N'-disalicylidene-1,2-phenylenediamine (H(2)ndsp) and NAP-disalicylidene ethylenediamine (H(2)salen) have been prepared and characterized by elemental analysis, electronic, IR, H-1 NMR and thermal studies. TG studies show that all complexes decomposed in one step. Kinetic and thermodynamic parameters were computed from the thermal decomposition data. The activation energy of complexes lies 60-87 kJ mol(-1) range. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2005.07.008