1,12-di-2-pyridyl-2,5,8,11-tetrathiadecane | 151777-56-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 1,12-di-2-pyridyl-2,5,8,11-tetrathiadecane
• 英文别名: 2,2'-(2,5,8,11-Tetrathiadodecane-1,12-diyl)dipyridine；2-[2-[2-[2-(pyridin-2-ylmethylsulfanyl)ethylsulfanyl]ethylsulfanyl]ethylsulfanylmethyl]pyridine
• CAS: 151777-56-9
• 化学式: C₁₈H₂₄N₂S₄
• 分子量: 396.666
• InChiKey: KSPDXZDQASIVFC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  24
• 可旋转键数：
  13
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  127
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  cobalt(II) tetrafluoroborate hexahydrate 、 1,12-di-2-pyridyl-2,5,8,11-tetrathiadecane 以 丙酮 为溶剂， 以50%的产率得到
  参考文献：
  名称：

  Complexes of cobalt, nickel, palladium and silver with N2Sx (x=3 or 4) ligands involving aromatic nitrogen and thioether donors

  摘要：

  Preparations of eleven complexes of the open-chain, aromatic nitrogen/thioether donor, N2S3 and N2S4 ligands, L1 and L2, are described. The complexes have been characterized by using conductivity, cyclic voltammetry, magnetic susceptibility, ESR, NMR and UV-Vis spectroscopies where appropriate and by X-ray crystallography for [Co(L2)][ClO4](2). Crystal data: monoclinic, space group C2/c, a=18.177(3), b=11.600(2), c=14.552(2) Angstrom, beta=124.703(6)degrees, Z=4, R=0.039, R-w=0.050. The presence of a spin-crossover system for the Co(II) complexes has been detected.

  DOI：

  10.1016/s0020-1693(96)05572-7

文献信息

• Adhikary, Bibhutosh; Liu, Shuang; Lucas, C. Robert, Inorganic Chemistry, 1993, vol. 32, # 26, p. 5957 - 5962
  作者：Adhikary, Bibhutosh、Liu, Shuang、Lucas, C. Robert

  DOI：——

  日期：——
• Complexes of cobalt, nickel, palladium and silver with N2Sx (x=3 or 4) ligands involving aromatic nitrogen and thioether donors
  作者：Bibhutosh Adhikary、Shuang Liu、C.Robert Lucas

  DOI：10.1016/s0020-1693(96)05572-7

  日期：1997.8

  Preparations of eleven complexes of the open-chain, aromatic nitrogen/thioether donor, N2S3 and N2S4 ligands, L1 and L2, are described. The complexes have been characterized by using conductivity, cyclic voltammetry, magnetic susceptibility, ESR, NMR and UV-Vis spectroscopies where appropriate and by X-ray crystallography for [Co(L2)][ClO4](2). Crystal data: monoclinic, space group C2/c, a=18.177(3), b=11.600(2), c=14.552(2) Angstrom, beta=124.703(6)degrees, Z=4, R=0.039, R-w=0.050. The presence of a spin-crossover system for the Co(II) complexes has been detected.