| 147834-30-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 147834-30-8
• 化学式: C₂₆H₂₆I₂MnP₂
• 分子量: 709.187
• InChiKey: JJUTVVVPRIIALI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  7.27
• 重原子数：
  31.0
• 可旋转键数：
  6.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  在 O₂ 作用下， 以 正戊烷 为溶剂， 以>99的产率得到MnI2(OPPh2Me)(PPh2Me)
  参考文献：
  名称：

  Controlled reaction of molecular oxygen with [Mnl₂(PPh₂Me)₂] to form the mixed phosphine–phosphine oxide complex [Mnl₂(OPPh₂Me)(PPh₂Me)] and the Bis(phosphine oxide) complex [Mnl₂(OPPh₂Me)₂]

  摘要：

  When a preformed solution of [MnI2(PPh2Me)2(O2)] in pentane at -40-degrees-C under argon was allowed to warm to room temperature, specific oxidation of one phosphine occurred and an almost quantitative yield of the mixed phosphine-phosphine oxide complex [MnI2(OPPh2Me) (PPh2Me)] was obtained; when the same procedure is followed under dry dioxygen the oxidation of both phosphines occurs and [MnI2(OPPh2Me)2] is obtained in almost quantitative yield. X-Ray crystallography showed both of these complexes to be pseudo-tetrahedral monomers, and [MnI2(OPPh2Me)(PPh2Me)] represents the first example of a mixed phosphine-phosphine oxide complex of manganese to be reported.

  DOI：

  10.1039/dt9930003373
• 作为产物：
  描述：

  manganese(II) iodide 、 二苯基甲氧基膦 以 正戊烷 为溶剂， 生成
  参考文献：
  名称：

  Controlled reaction of molecular oxygen with [Mnl₂(PPh₂Me)₂] to form the mixed phosphine–phosphine oxide complex [Mnl₂(OPPh₂Me)(PPh₂Me)] and the Bis(phosphine oxide) complex [Mnl₂(OPPh₂Me)₂]

  摘要：

  When a preformed solution of [MnI2(PPh2Me)2(O2)] in pentane at -40-degrees-C under argon was allowed to warm to room temperature, specific oxidation of one phosphine occurred and an almost quantitative yield of the mixed phosphine-phosphine oxide complex [MnI2(OPPh2Me) (PPh2Me)] was obtained; when the same procedure is followed under dry dioxygen the oxidation of both phosphines occurs and [MnI2(OPPh2Me)2] is obtained in almost quantitative yield. X-Ray crystallography showed both of these complexes to be pseudo-tetrahedral monomers, and [MnI2(OPPh2Me)(PPh2Me)] represents the first example of a mixed phosphine-phosphine oxide complex of manganese to be reported.

  DOI：

  10.1039/dt9930003373

文献信息

• The reaction of bromo- and iodo-phosphoranes with unactivated coarse grain manganese metal powder to yield [MnI₂(phosphine)₂] and [{MnX₂(phosphine)}_n](X = Br or I) by insertion of Mn into the P–X bond. The crystal structure of [MnI₂(PPh₃)₂]
  作者：Stephen M. Godfrey、Charles A. McAuliffe、Robin G. Pritchard

  DOI：10.1039/dt9930000371

  日期：——

  The novel reaction of crude manganese metal powder with dibromo- and diiodo-phosphoranes, R3PX2, has been studied. Reaction of the phosphoranes R3PI2 (R = phenyl or substituted aryl) with manganese allows insertion of the metal into P-X bonds and gives the monomeric tetrahedral complexes [MnI2(PR3)2] and MnI2. However, reaction of R3PX2 (R3 = mixed aryl/alkyl, trialkyl; X = Br or I) with manganese, whilst once again proceeding via insertion into P-X bonds, now leads to the quantitative isolation of the polymeric complexes [MnX2(PR3)}n], thus illustrating the subtle nature of these reactions. Examples of both types of complex have been crystallographically characterised and represent rare examples of such. There is some evidence that where R3 = Ph2Me an equilibrium exists and both types of complex, [MnI2(PPh2Me)2] and [MnI2(PPh2Me)}n] can be detected from the same reaction.