docosyl-2-(2-pyridyl)benzimidazole | 887305-51-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: docosyl-2-(2-pyridyl)benzimidazole
• 英文别名: 1-Docosyl-2-pyridin-2-ylbenzimidazole
• CAS: 887305-51-3
• 化学式: C₃₄H₅₃N₃
• 分子量: 503.815
• InChiKey: RKLDSWBQHKBKJG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13
• 重原子数：
  37
• 可旋转键数：
  22
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  30.7
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 顺-双(2,2-二吡啶)二氯化钌(II) 水合物 、 docosyl-2-(2-pyridyl)benzimidazole 以 水 、 乙二醇 为溶剂， 生成 [Ru(2,2'-bipyridine)2(docosyl-2-(2-pyridyl)benzimidazole)](PF6)2
  参考文献：
  名称：

  Studies of Langmuir−Blodgett Films of an Ion Pair Metal Complex Containing Eu(III)-Ru(II) Dual Chromophores

  摘要：

  A surfactant ion-pair complex, [Ru(bPY)(2)L] [Eu(NTA)(4)](2) (in which L = 1-docosyl-2-(2-pyfidyl)benzimidazole, bpy = 2,2 '-bipyridine, and NTA = 4,4,4-trifluoro-1-(2-naphthyl)-1,3-butanedionato) has been synthesized. The surface pressure-area isotherm measurements show that the complex forms a stable Langmuir film at the air-water interface without adding any electrolytes into the subphase. The monolayers formed at the surface pressures of 5 mN m(-1) and 20 mN m(-1), have been successfully transferred onto glass and quartz substrates with the transfer ratios close to unity. The Lanumuir-Blodgett films were studied by UV-visible, infrared, and emission spectroscopies, atomic force microscopy, and cyclic voltammetry. The optical, redox, and morphology properties of the LB films were found to be significantly affected by the target surface pressures used for the film depositions.

  DOI：

  10.1021/jp054525v