| 562069-95-8

• 分子结构分类: 有机化合物
• CAS: 562069-95-8
• 化学式: C₄₀H₁₀₈In₄PdSi₁₂
• 分子量: 1492.02
• InChiKey: BGBOSOQTDRFHJT-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  (N,N,N',N'-tetramethylethylenediamine)dimethylpalladium(II) 、 Indium, [tris(trimethylsilyl)methyl]- 以 正己烷 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  [M(GaCp*)₄] (M = Pd, Pt) as Building Blocks for Dimeric Homoleptic Cluster Compounds of the Type [MPt(GaCp*)₅]

  摘要：

  The monomeric homoleptic Pt(O) complex [Pt(GaCp*)(4)] (1) has been synthesized by reaction of [Pt(COD)(2)] with GaCp* in hexane. The monomeric homoleptic NO complexes [Pd(GaCp*)(4)] (2) and [Pd{InC(SiMe3)(3)}(4)] (3) are accessible by reaction of [Pd(tmeda)(CH3)(2)] with GaCp* and [InC(SiMe3)(3)], respectively. These reactions were shown to proceed via methyl group transfer from palladium to indium. or gallium, respectively. Complexes 1 and 2 can be used as building blocks for the synthesis of dinuclear cluster compounds. Thus, reaction of [Pt(COD)(2)] with 1 or 2 and subsequent addition of GaCp* yields [Pt-2(GaCp*)(2)(mu(2)-GaCp*)(3)] (4a) and [PtPd(GaCp*)(mu(2)-GaCp*)(3)] (5a). Intermediates of this dimerization reactions, i.e., [Pt-2(GaCp*)(mu(2)-GaCp*)(3)(eta(2)-COD)] (4b) and [PtPd(GaCp*)(mu(2)-GaCp*)(3)(eta(2)-COD)](5b), were isolated and characterized by means of variable-temperature NMR spectroscopy.

  DOI：

  10.1021/om021003i