摩熵化学
数据库官网
小程序
打开微信扫一扫
首页 分子通 化学资讯 化学百科 反应查询 关于我们
请输入关键词

4-溴-3,5-二氯苯甲酸甲酯 | 117738-81-5

中文名称
4-溴-3,5-二氯苯甲酸甲酯
中文别名
——
英文名称
methyl 4-bromo-3,5-dichlorobenzoate
英文别名
——
4-溴-3,5-二氯苯甲酸甲酯化学式
CAS
117738-81-5
化学式
C8H5BrCl2O2
mdl
MFCD14704248
分子量
283.937
InChiKey
OLCZJLAQCXIXNW-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    3.7
  • 重原子数:
    13
  • 可旋转键数:
    2
  • 环数:
    1.0
  • sp3杂化的碳原子比例:
    0.12
  • 拓扑面积:
    26.3
  • 氢给体数:
    0
  • 氢受体数:
    2

上下游信息

  • 上游原料
    中文名称 英文名称 CAS号 化学式 分子量
  • 下游产品
    中文名称 英文名称 CAS号 化学式 分子量

反应信息

  • 作为反应物:
    参考文献:
    名称:
    Pesticidal compounds
    摘要:
    这个公式中的双环辛烷杀虫剂是通过环化反应制备的。在这些公式中,R可以是各种有机基团,最好是正丁基或正丙基,而R²是多取代苯基。
    公开号:
    EP0279698A3
  • 作为产物:
    参考文献:
    名称:
    Pesticidal compounds
    摘要:
    这个公式中的双环辛烷杀虫剂是通过环化反应制备的。在这些公式中,R可以是各种有机基团,最好是正丁基或正丙基,而R²是多取代苯基。
    公开号:
    EP0279698A3
点击查看最新优质反应信息

文献信息

  • Heterocyclic pesticidal compounds
    申请人:The Wellcome Foundation
    公开号:US05502073A1
    公开(公告)日:1996-03-26
    Compounds of the formula (I) ##STR1## which contain between 10 and 27 carbon atoms, and wherein m and n are independently selected from 0, 1 and 2; R.sup.2a is hydrogen, methyl, or ethyl; R.sup.2b is acetylene or contains between 3 and 18 carbon atoms and is a group R.sup.7, wherein R.sup.7 is a C.sub.1-13 non-aromatic hydrocarbyl group, optionally substituted by a cyano or C.sub.1-4 carbalkoxy group and/or by one or two hydroxy groups and/or by one to five halo atoms which are the same or different and/or by one to three groups R.sup.8 which are the same or different and each contain one to four hetero atoms, which are the same or different and are chosen from oxygen, sulphur, nitrogen and silicon, 1 to 10 carbon atoms and optionally 1 to 6 fluoro or chloro atoms or R.sup.2b is a 6-membered aromatic ring substituted by cyano and/or by one to three groups R.sup.8 and/or by a group --C.tbd.CH, --C.tbd.C-R.sup.7 or C.tbd.C-halo and/or by one to five halo atoms and/or by one to three C.sub.1-4 haloalkyl groups wherein R.sup.7 and R.sup.8 are as hereinbefore defined; R.sup.4 and R.sup.6 are the same or different and are chosen from hydrogen, methyl, trifluoromethyl or cyano; and R.sup.5 is hydrogen or methyl provided that R.sup.2b is not propyl or butyl are described which have pesticidal activity, particularly against arthropod pests. Pesticidal formulations containing the compounds of the formula (I), their use in the control of pests and method for their preparation are also disclosed.
    化学式(I)##STR1##中含有10至27个碳原子,其中m和n分别选自0、1和2;R.sup.2a为氢、甲基或乙基;R.sup.2b为乙炔或含有3至18个碳原子且为基团R.sup.7,其中R.sup.7为C.sub.1-13非芳香烃基团,可选择地被氰基或C.sub.1-4羰基烷氧基团取代和/或被一个或两个羟基取代和/或被一个到五个相同或不同的卤原子取代和/或被一个到三个相同或不同的基团R.sup.8取代,每个基团R.sup.8含有一个到四个相同或不同的杂原子,这些杂原子选自氧、硫、氮和硅,1至10个碳原子和可选择地1至6个氟或氯原子,或R.sup.2b为被氰基取代的6元芳环和/或被一个到三个基团R.sup.8取代和/或为基团--C.tbd.CH、--C.tbd.C-R.sup.7或C.tbd.C-卤基取代和/或被一个到五个卤原子取代和/或被一个到三个C.sub.1-4卤代烷基团取代,其中R.sup.7和R.sup.8如前所定义;R.sup.4和R.sup.6相同或不同,选自氢、甲基、三氟甲基或氰基;R.sup.5为氢或甲基,前提是R.sup.2b不是丙基或丁基,描述了具有杀虫活性的化合物,特别是对节肢动物害虫。还公开了含有化合物(I)的杀虫配方,其在害虫控制中的使用以及其制备方法。
  • Method for preparing aromatic compounds
    申请人:ROHM AND HAAS COMPANY
    公开号:EP0825173A1
    公开(公告)日:1998-02-25
    A method for synthesizing aromatic compounds by selectively dehalogenating aromatic starting materials is provided. Compounds may be prepared which are substituted with fluoro, chloro or bromo. The method may be used to remove halogen atoms from sites at which halogenation is not desired, and to form substantially pure halogenated compounds from mixtures of starting materials. The method uses a copper containing dehalogenation agent and an acid with the dehalogenation being controlled by a substituent such as a carboxylic acid, amide, ester, aldehyde, ketone or cyano on the aromatic ring.
    提供了一种通过选择性地脱卤芳香族起始材料来合成芳香族化合物的方法。可以制备被氟、氯或溴取代的化合物。该方法可用于从不需要卤素化的位置去除卤素原子,并从起始材料的混合物中形成基本上纯净的卤代化合物。该方法使用含有铜的脱卤素剂和酸,脱卤素作用通过芳香环上的取代基如羧酸、酰胺、酯、醛、酮或腈来控制。
  • PESTICIDAL COMPOSITIONS AND PROCESSES RELATED THERETO
    申请人:Dow AgroSciences LLC
    公开号:US20150353477A1
    公开(公告)日:2015-12-10
    This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Nematoda, Arthropoda, and/or Mollusca, processes to produce such molecules and intermediates used in such processes, compositions containing such molecules, and processes of using such molecules against such pests. These molecules may be used, for example, as nematicides, acaricides, insecticides, miticides, and/or molluscicides. This document discloses molecules having the following formula (“Formula One”).
    这份披露涉及具有对线虫门、节肢动物门和/或软体动物门害虫具有杀虫效用的分子领域,用于生产此类分子和用于此类过程的中间体,含有此类分子的组合物,以及使用此类分子对抗此类害虫的过程。这些分子可以用作线虫杀虫剂、螨虫杀虫剂、杀虫剂、螨虫剂和/或软体动物杀虫剂。本文件披露了具有以下式(“式一”)的分子。
  • Pesticidal compositions and processes related thereto
    申请人:Dow AgroSciences LLC
    公开号:US09226501B2
    公开(公告)日:2016-01-05
    This document discloses molecules having the following formula (“Formula One”): and processes associated therewith.
    这份文件揭示了具有以下公式(“公式一”)的分子及其相关的过程。
  • Novel heterocyclic pesticidal compounds
    申请人:THE WELLCOME FOUNDATION LIMITED
    公开号:EP0294229A2
    公开(公告)日:1988-12-07
    Compounds of the formula (I) which contain between 10 and 27 carbon atoms, and wherein m and n are independently selected from 0, 1 and 2; R2a is hydrogen, methyl, or ethyl; R2b is acetylene or contains between 3 and 18 carbon atoms and is a group R7, wherein R7 is a C1-13 non-aromatic hydrocarbyl group, optionally substituted by a cyano or Ci-4 carbalkoxy group and/or by one or two hydroxy groups and/or by one to five halo atoms which are the same or different and/or by one to three groups R8 which are the same or different and each contain one to four hetero atoms, which are the same or different and are chosen from oxygen, sulphur, nitrogen and silicon, 1 to 10 carbon atoms and optionally 1 to 6 fluoro or chloro atoms or R2b is a 6-membered aromatic ring substituted by cyano and/or by one to three groups R8 and/or by a group -C≡CH, -C≡C-R7 or C≡C-halo and/or by one to five halo atoms and/or by one to three Ci-4 haloalkyl groups wherein R7 and R8 are as hereinbefore defined; R4 and R6 are the same or different and are chosen from hydrogen, methyl, trifluoromethyl or cyano; and R5 is hydrogen or methyl provided that R2b is not propyl or butyl are described which have pesticidal activity, particularly against arthropod pests. Pesticidal formulations containing the compounds of the formula (I), their use in the corttrol of pests and method for their preparation are also disclosed,
    式 (I) 的化合物 其中 m 和 n 独立地选自 0、1 和 2; R2a 是氢、甲基或乙基;R2b 是炔基或含有 3 至 18 个碳原子且是基团 R7,其中 R7 是 C1-13 非芳香族烃基,任选被氰基或 Ci-4 碳烷氧基和/或一个或两个羟基和/或一至五个相同或不同的卤原子和/或一至三个相同或不同且各含有一至四个杂原子的基团 R8 取代、或 R2b 是被氰基和/或被 1 至 3 个基团 R8 和/或被基团-C≡CH、-C≡C-R7 或 C≡C-halo 和/或被 1 至 5 个卤原子和/或被 1 至 3 个 Ci-4 卤烷基取代的 6 元芳香环,其中 R7 和 R8 如前定义;R4和R6相同或不同,选自氢、甲基、三氟甲基或氰基;R5为氢或甲基,但R2b不是丙基或丁基。还公开了含有式(I)化合物的杀虫制剂、其在防治害虫中的用途及其制备方法、
查看更多

同类化合物

(βS)-β-氨基-4-(4-羟基苯氧基)-3,5-二碘苯甲丙醇 (S)-(-)-7'-〔4(S)-(苄基)恶唑-2-基]-7-二(3,5-二-叔丁基苯基)膦基-2,2',3,3'-四氢-1,1-螺二氢茚 (S)-盐酸沙丁胺醇 (S)-3-(叔丁基)-4-(2,6-二甲氧基苯基)-2,3-二氢苯并[d][1,3]氧磷杂环戊二烯 (S)-2,2'-双[双(3,5-三氟甲基苯基)膦基]-4,4',6,6'-四甲氧基联苯 (S)-1-[3,5-双(三氟甲基)苯基]-3-[1-(二甲基氨基)-3-甲基丁烷-2-基]硫脲 (R)富马酸托特罗定 (R)-(-)-盐酸尼古地平 (R)-(+)-7-双(3,5-二叔丁基苯基)膦基7''-[((6-甲基吡啶-2-基甲基)氨基]-2,2'',3,3''-四氢-1,1''-螺双茚满 (R)-3-(叔丁基)-4-(2,6-二苯氧基苯基)-2,3-二氢苯并[d][1,3]氧杂磷杂环戊烯 (R)-2-[((二苯基膦基)甲基]吡咯烷 (N-(4-甲氧基苯基)-N-甲基-3-(1-哌啶基)丙-2-烯酰胺) (5-溴-2-羟基苯基)-4-氯苯甲酮 (5-溴-2-氯苯基)(4-羟基苯基)甲酮 (5-氧代-3-苯基-2,5-二氢-1,2,3,4-oxatriazol-3-鎓) (4S,5R)-4-甲基-5-苯基-1,2,3-氧代噻唑烷-2,2-二氧化物-3-羧酸叔丁酯 (4-溴苯基)-[2-氟-4-[6-[甲基(丙-2-烯基)氨基]己氧基]苯基]甲酮 (4-丁氧基苯甲基)三苯基溴化磷 (3aR,8aR)-(-)-4,4,8,8-四(3,5-二甲基苯基)四氢-2,2-二甲基-6-苯基-1,3-二氧戊环[4,5-e]二恶唑磷 (2Z)-3-[[(4-氯苯基)氨基]-2-氰基丙烯酸乙酯 (2S,3S,5S)-5-(叔丁氧基甲酰氨基)-2-(N-5-噻唑基-甲氧羰基)氨基-1,6-二苯基-3-羟基己烷 (2S,2''S,3S,3''S)-3,3''-二叔丁基-4,4''-双(2,6-二甲氧基苯基)-2,2'',3,3''-四氢-2,2''-联苯并[d][1,3]氧杂磷杂戊环 (2S)-(-)-2-{[[[[3,5-双(氟代甲基)苯基]氨基]硫代甲基]氨基}-N-(二苯基甲基)-N,3,3-三甲基丁酰胺 (2S)-2-[[[[[[((1R,2R)-2-氨基环己基]氨基]硫代甲基]氨基]-N-(二苯甲基)-N,3,3-三甲基丁酰胺 (2-硝基苯基)磷酸三酰胺 (2,6-二氯苯基)乙酰氯 (2,3-二甲氧基-5-甲基苯基)硼酸 (1S,2S,3S,5S)-5-叠氮基-3-(苯基甲氧基)-2-[(苯基甲氧基)甲基]环戊醇 (1-(4-氟苯基)环丙基)甲胺盐酸盐 (1-(3-溴苯基)环丁基)甲胺盐酸盐 (1-(2-氯苯基)环丁基)甲胺盐酸盐 (1-(2-氟苯基)环丙基)甲胺盐酸盐 (-)-去甲基西布曲明 龙胆酸钠 龙胆酸叔丁酯 龙胆酸 龙胆紫 龙胆紫 齐达帕胺 齐诺康唑 齐洛呋胺 齐墩果-12-烯[2,3-c][1,2,5]恶二唑-28-酸苯甲酯 齐培丙醇 齐咪苯 齐仑太尔 黑染料 黄酮,5-氨基-6-羟基-(5CI) 黄酮,6-氨基-3-羟基-(6CI) 黄蜡,合成物 黄草灵钾盐