[Cu(bis(diphenylphosphino)ethane)(2-thenoyltrifluoroacetonate)]2 | 351056-06-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Cu(bis(diphenylphosphino)ethane)(2-thenoyltrifluoroacetonate)]2
• 英文别名: [Cu(dppe)(tfac)]2
• CAS: 351056-06-9
• 化学式: C₆₈H₅₆Cu₂F₆O₄P₄S₂
• 分子量: 1366.3
• InChiKey: DPAZWSVTUMRBFM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-噻吩甲酰三氟丙酮 、 铜 、 1,2-双(二苯基膦)乙烷 以 丙酮 为溶剂， 以79%的产率得到[Cu(bis(diphenylphosphino)ethane)(2-thenoyltrifluoroacetonate)]2
  参考文献：
  名称：

  Synthesis of copper(I) β-diketone complexes

  摘要：

  At room temperature, the reaction of metallic copper powder with 2-thenoyltrifluoroacetone (tfac) and selected phosphine ligands gives the new copper(I) complexes [Cu(PPh3)(2)(tfac)] (1), [Cu(dppm)-(tfac)](2) (2), [Cu(dppe)(tfac)](2) (3), [Cu(dppp)(tfac)] (4), [Cu(dppb)-(tfac)](2) (5), Ph2P(CH2)(n)PPh2 [n = 1 (dppm), 2 (dppe), 3 (dppp), 4 (dppb)]. These complexes have been characterized by physicochemical and spectroscopic methods. X-ray structure analysis of 1 and 3 shows that tfac behaves as a chelating ligand and dppe coordinates as a bridging bidentate ligand to Cu(I) atoms in the Cu(I) complexes. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0277-5387(01)00715-x

文献信息

• Dongmei, Wang; Ruina, Yang; Yingfan, Liu, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical
  作者：Dongmei, Wang、Ruina, Yang、Yingfan, Liu、Douman, jin

  DOI：——

  日期：——