[Co2(1,1'-biphenyl-2,2'-dicarboxylic acid-2H)2(2,2'-bipyridine)2(H2O)2] | 1204325-61-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Co2(1,1'-biphenyl-2,2'-dicarboxylic acid-2H)2(2,2'-bipyridine)2(H2O)2]
• 英文别名: [Co2(dpa)2(2,2'-bpy)2(H2O)2]
• CAS: 1204325-61-0
• 化学式: C₄₈H₃₆Co₂N₄O₁₀
• 分子量: 946.821
• InChiKey: BEWAMXMWYXQVMR-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  水 、 2,2'-联吡啶 、 cobalt(II) diacetate tetrahydrate 、 2,2'-联苯二甲酸 在 NaOH 作用下， 以 水 为溶剂， 以52%的产率得到[Co2(1,1'-biphenyl-2,2'-dicarboxylic acid-2H)2(2,2'-bipyridine)2(H2O)2]
  参考文献：
  名称：

  Synthesis, characterization and properties of series coordination polymers constructed from a biphenyl dicarboxylate and nitrogen-containing mixed ligands

  摘要：

  A series of coordination polymers have been prepared by the combination of flexible ligand 1,1'-biphenyl-2,2'-dicarboxylic acid (H(2)dpa) and different types of nitrogen-containing ligands, with various metal ions such as Co(II), Zn(II) and Cd(II). The single-crystal structure analyses reveal that the above complexes possess different structure features with the introduction of different nitrogen-containing ligands. When auxiliary linear ligand 4,4'-bipyridine (4,4'-bpy) is introduced, two-dimensional layered complex, [Co-2(dpa)(2)(4,4'-bpy)(2)(H2O)](n) (1) is formed. Whereas if chelating ligand, 1,10-phenanthroline (1,10'-phen) and 2,2'-bipyridine (2,2'-bpy) are introduced, one-dimensional complex [Zn(dpa)(1,10'-phen)](n) (2) and discrete complexes [Co-2(dpa)(2)(2,2'-bpy)(2)(H2O)(2)] (3), [Co-3(dpa)(3)(1,10'-phen)(6)(H2O)(2)] (4), [Cd(dpa)(1,10'-phen)(2)][(H(2)dpa)(2)(H2O)(2)] (5) are synthesized. To our interest, 1 and 2 crystallize in homochiral space-group. Furthermore, the magnetic property of complex 1 and the fluorescent properties of complexes 2 and 5 are studied. Crown Copyright (C) 2009 Published by Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.09.025