nickel(II)-4,4',4'',4'''-phthalocyanine tetracarboxylic acid | 74427-88-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: nickel(II)-4,4',4'',4'''-phthalocyanine tetracarboxylic acid
• 英文别名: nickel-4,4',4'',4'''-tetracarboxyphthalocyanine；(4,4',4'',4'''-Tetracarboxyphthalocyaninato)nickel；2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13(18),14,16,19(39),20,22(27),23,25,28,30(37),31(36),32,34-nonadecaene-6,15,24,33-tetracarboxylate;hydron;nickel(2+)
• CAS: 74427-88-6
• 化学式: C₃₆H₁₆N₈NiO₈
• 分子量: 747.262
• InChiKey: RYWZWFYGVVRUJD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  nickel(II)-4,4',4'',4'''-phthalocyanine tetracarboxylic acid 以 neat (no solvent) 为溶剂， 生成 nickel(II) tetra-tert-butylphthalocyanine
  参考文献：
  名称：

  Studies on phthalocyanine sheet polymers

  摘要：

  Cobalt, nickel and copper phthalocyanine sheet polymers are synthesized by heating their respective metal (II) phthalocyanine tetracarboxylic acids at 400 degreesC in nitrogen atmosphere. These polymers are characterized using UV-Visible spectra, IR spectra, magnetic susceptibility.. X-ray powder diffraction and thermogravimetric analysis. Electrical conductivity studies are carried out using two-probe technique in the temperature range 25-200 degreesC for each polymer. These polymeric materials showed room temperature electrical conductivity 10-1000 times higher values compared to earlier reported values for this type of sheet polymers. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.05.017
• 作为产物：
  描述：

  3,4-dicyanobenzoic acid 、 nickel diacetate 以 further solvent(s) 为溶剂， 以10-15的产率得到nickel(II)-4,4',4'',4'''-phthalocyanine tetracarboxylic acid
  参考文献：
  名称：

  Solov'eva, L. I.; Luk'yanets, E. A., Journal of general chemistry of the USSR, 1980, vol. 50, p. 907 - 915

  摘要：

  DOI：

文献信息

• Carboxy-substituted Phthalocyanine Metal Complexes
  作者：G. P. Shaposhnikov、V. E. Maizlish、V. P. Kulinich

  DOI：10.1007/s11176-005-0450-4

  日期：2005.9

  Metal complexes of carboxy-substituted phthalocyanines differing in the number of carboxy groups and their positions and those having carboxy groups together with other substituents were synthesized, and their spectral and some other properties were studied.

  合成了不同数量和位置的羧基取代酞菁金属配合物，以及同时具有羧基和其他取代基的化合物，并对它们的光谱及其他一些性质进行了研究。
• Synthesis, Characterization, Novel Interaction of DNA, Antioxidant and Antimicrobial Studies of New Water Soluble Metallophthalocyanines Posture Eight Hydroxyphenyl Moiety via 1,3,4-oxadiazole Bridge
  作者：Chidananda Basappa、Venugopala K. R. Reddy、Harish M. N. Kotresh、Pradeep K. Musturappa、Mruthyunjayachari C. Devendrachari、Shimoga D. Ganesh

  DOI：10.1002/jhet.2269

  日期：2015.11

  substituted MPc complexes. The successful synthesis of these novel water soluble MPc moieties were employed as an effective DNA binding with calf thymus DNA was monitored using ultraviolet−visible spectral titrations and cleavage pBR322 DNA conceded in the absence of reductant by agarose gel electrophoresis method. The results indicate that all these water soluble complexes significantly show excellent

  新的外围设备2（3），9（10），16（17），23（24）-tetra-5- [4,4'-二酚]-苯基-[1,3,4]-恶二唑取代的金属酞菁（ MPc）复合体已经过精心设计和执行。由于高的结合和在水中的极好的溶解性，使其在DNA结合和裂解研究中具有潜在的用途。傅里叶变换红外光谱，核磁共振，电子自旋电离质谱数据和元素分析证实了这些取代的MPc配合物的定义明确的鞍状扭曲结构。这些新颖的水溶性MPc部分的成功合成被用作与小牛胸腺DNA的有效DNA结合，使用紫外可见光谱滴定法进行监测，并通过琼脂糖凝胶电泳法在不存在还原剂的情况下裂解pBR322 DNA。结果表明，所有这些水溶性复合物均显着表现出优异的结合和适度的裂解敏感性活性。值得注意的是图6和7显示出与其他水溶性酞菁类相比潜在的抗微生物和明显的抗氧化活性。
• Synthesis, Spectroscopic Investigation and Catalytic Behaviour of Histidine Substituted Nickel(II) Phthalocyanine
  作者：K.R. Venugopala Reddy、T.M. Sharanakumar、Mounesh、N.Y. Praveenkumar、Suresh、N.H.M Nandinibaby

  DOI：10.14233/ajchem.2021.23202

  日期：——

  In this work, the oxidation behaviour of phenol and chlorophenol contaminants present in the water catalyzed by histidine substituted nickel(II) phthalocyanine (NiPc) is reported. This work comprises synthesis, characterization and study the catalytic behaviour of histidine substituted NiPc on the oxidation of phenol and their substrates like 2- and 4-chlorophenols with 4-aminoantipyrine utilizing

  在这项工作中，报道了组氨酸取代的酞菁镍 (II) (NiPc) 催化水中存在的苯酚和氯酚污染物的氧化行为。这项工作包括合成、表征和研究组氨酸取代的 NiPc 对苯酚及其底物（如 2- 和 4-氯苯酚）与 4-氨基安替比林利用分子氧氧化的催化行为。氧化产物可以通过紫外-可见光谱进行分析，结果证实超氧阴离子自由基的形成对于产物的形成至关重要，并且可行的机制包括单电子从酚类化合物通过轴连续转移到O2。报道了组氨酸 Ni(II)Pc。
• Novel nitrogen‐rich anchored nickel (II) phthalocyanine with composite of multiwalled carbon nanotubes on modified glassy carbon electrode: Sensitive and selective electrocatalytic activity of nitrite
  作者：Mounesh、K. R. Venugopala Reddy、Anup Pandith、Gaber E. Eldesoky、Bhari Mallanna Nagaraja

  DOI：10.1002/aoc.7302

  日期：2024.1

  by multiwalled carbon nanotubes, a cyclic voltammetry (CV), differential pulse voltammetry (DPV), and amperometric techniques utilized for nitrite sensor were developed. The sensor exhibited a fast response towards nitrite with a detection limit of 3.012 nM and a linear concentration range of 50–900 nM by the CV method. The fabricated sensor shows excellent electrocatalytic activity compared with the

  这项工作描述了新型四取代镍 6-溴苯并噻唑甲酰胺镍 (II) 酞菁 (NiTBBTCAPC) 的合成，并通过光谱-显微方法和电化学分析进行了证实。由于 NiTBBCAPC-多壁碳纳米管（MWCNTs）/玻碳电极（GCE）比裸 GCE 和 NiTBBCAPC/GCE 具有更好的电子传输能力，因此研究了亚硝酸盐的电化学氧化。由于多壁碳纳米管增加了 GCE 的表面积，因此开发了用于亚硝酸盐传感器的循环伏安法 (CV)、差分脉冲伏安法 (DPV) 和安培技术。该传感器对亚硝酸盐表现出快速响应，CV 方法的检测限为 3.012 nM，线性浓度范围为 50–900 nM。与具有多壁碳纳米管复合材料的PC修饰电极相比，所制造的传感器对亚硝酸盐的氧化表现出优异的电催化活性。即使在过量抗坏血酸 (AA)、多巴胺 (DA)、尿酸 (UA)、扑热息痛 (PA)、葡萄糖、Pb (II)、镉 (II)、钙 (II)
• Decorating nickel phthalocyanine periphery by aryl-,,-oxadiazole pendants: synthesis, characterization, and conductivity studies
  作者：M.N.K. Harish、J. Keshavayya、K.R. Venugopala Reddy、H.R. Mallikarjuna、R.A. Shoukat Ali、T. Rajesh

  DOI：10.1080/00958972.2010.529902

  日期：2010.12.10

  We have decorated nickel phthalocyanine (NiPc) periphery by four different aryl-[1,3,4]-oxadiazole pendants. Introduction of aryl-[1,3,4]-oxadiazole pendants into the NiPc core results in improved thermal stability, fine-tuning of the position of the Q-band with decrease in band gap, indicating effective electronic communication between the two different ring systems with NiPc core. The magnitude of DC electrical conductivity for aryl-[1,3,4]-oxadiazole-substituted NiPcs 3a-3d is found to be 105 times higher than the parent NiPc (1). The temperature-dependent DC conductivity studies reveal semiconducting nature of the newly synthesized NiPc compounds with significant decrease in thermal activation energy (E) compared to parent NiPc.