{Pt(Ph2PCH2CH2NH-t-Bu)(Ph2PCH2CH2NH-t-Bu)Cl}Cl | 685822-91-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: {Pt(Ph2PCH2CH2NH-t-Bu)(Ph2PCH2CH2NH-t-Bu)Cl}Cl
• CAS: 685822-91-7；134343-71-8
• 化学式: C₃₆H₄₈ClN₂P₂Pt*Cl
• 分子量: 836.724
• InChiKey: YUUPHOMISXHVPI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  盐酸 、 {Pt(Ph2PCH2CH2NH-t-Bu)(Ph2PCH2CH2NH-t-Bu)Cl}Cl 以 甲醇 为溶剂， 生成 Pt(Ph2PCH2CH2NH-t-Bu*HCl)2Cl2
  参考文献：
  名称：

  Metal complexes of functionalized phosphines-I. Synthesis and characterization of 2-diphenylphosphinoethylamines and some of their complexes with platinum. X-ray structure of [HBut)(Ph2PCH2CH2NHBut·HCl)Cl]Cl·H2O

  摘要：

  The new bidentate ligands Ph2PCH2CH2NHR [R = Bu(t), CH2Ph, CH(Me) Ph] and Ph2PCH2CH2N(CH2Ph)2 and their corresponding hydrochloride salts have been synthesized and were characterized by H-1, P-31-{H-1} and C-13-{H-1} NMR spectroscopy. The ligand Ph2PCH2CH2NHBu(t) reacts with K2PtCl4 or (COD)PtCl2 to form [P activated t(Ph2PCH2CH2NHBu(t))(Ph2PCH2CH2NHBu(t).HCl)Cl]Cl whose structure has been determined by X-ray diffraction. Treatment of this complex with HCl gas gives [Pt(Ph2PCH2CH2NHBu(t).HCl)2Cl2] which can also be synthesized from Ph2PCH2CH2NHBu(t).HCl and K2PtCl4.

  DOI：

  10.1016/s0277-5387(00)80220-x
• 作为产物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 [2-(Diphenylphosphino)ethyl]-tert-butylamine 以 二氯甲烷 为溶剂， 以75%的产率得到{Pt(Ph2PCH2CH2NH-t-Bu)(Ph2PCH2CH2NH-t-Bu)Cl}Cl
  参考文献：
  名称：

  Metal complexes of functionalized phosphines-I. Synthesis and characterization of 2-diphenylphosphinoethylamines and some of their complexes with platinum. X-ray structure of [HBut)(Ph2PCH2CH2NHBut·HCl)Cl]Cl·H2O

  摘要：

  The new bidentate ligands Ph2PCH2CH2NHR [R = Bu(t), CH2Ph, CH(Me) Ph] and Ph2PCH2CH2N(CH2Ph)2 and their corresponding hydrochloride salts have been synthesized and were characterized by H-1, P-31-{H-1} and C-13-{H-1} NMR spectroscopy. The ligand Ph2PCH2CH2NHBu(t) reacts with K2PtCl4 or (COD)PtCl2 to form [P activated t(Ph2PCH2CH2NHBu(t))(Ph2PCH2CH2NHBu(t).HCl)Cl]Cl whose structure has been determined by X-ray diffraction. Treatment of this complex with HCl gas gives [Pt(Ph2PCH2CH2NHBu(t).HCl)2Cl2] which can also be synthesized from Ph2PCH2CH2NHBu(t).HCl and K2PtCl4.

  DOI：

  10.1016/s0277-5387(00)80220-x