N8,N8,N20,N20-Tetraethyl-2,2,14,14-tetramethyl-7,9,19,21-tetraoxa-8,20-diphosphapentacyclo-[20.2.2.2^3,6.2^10,13.2^15,18]dotriaconta-1(24),3,5,10,12,15,17,22,25,27,29,31-dodecaen-8,20-diamin | 272460-92-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N8,N8,N20,N20-Tetraethyl-2,2,14,14-tetramethyl-7,9,19,21-tetraoxa-8,20-diphosphapentacyclo-[20.2.2.2^3,6.2^10,13.2^15,18]dotriaconta-1(24),3,5,10,12,15,17,22,25,27,29,31-dodecaen-8,20-diamin
• 英文别名: 8-N,8-N,20-N,20-N-tetraethyl-2,2,14,14-tetramethyl-7,9,19,21-tetraoxa-8,20-diphosphapentacyclo[20.2.2.23,6.210,13.215,18]dotriaconta-1(24),3(32),4,6(31),10(30),11,13(29),15,17,22,25,27-dodecaene-8,20-diamine
• CAS: 272460-92-1
• 化学式: C₃₈H₄₈N₂O₄P₂
• 分子量: 658.758
• InChiKey: VSSARDHBUIYLKW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.7
• 重原子数：
  46.0
• 可旋转键数：
  6.0
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  43.4
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  N8,N8,N20,N20-Tetraethyl-2,2,14,14-tetramethyl-7,9,19,21-tetraoxa-8,20-diphosphapentacyclo-[20.2.2.2^3,6.2^10,13.2^15,18]dotriaconta-1(24),3,5,10,12,15,17,22,25,27,29,31-dodecaen-8,20-diamin 在 sulfur 作用下， 生成 bis(O,O'-isopropylidenedi-p-phenylene) bis(diethylphosphorothioamidate)
  参考文献：
  名称：

  摘要：

  DOI：

  10.1023/a:1013262120747
• 作为产物：
  描述：

  双酚A 、 六乙基亚磷酸胺 生成 N8,N8,N20,N20-Tetraethyl-2,2,14,14-tetramethyl-7,9,19,21-tetraoxa-8,20-diphosphapentacyclo-[20.2.2.2^3,6.2^10,13.2^15,18]dotriaconta-1(24),3,5,10,12,15,17,22,25,27,29,31-dodecaen-8,20-diamin
  参考文献：
  名称：

  摘要：

  DOI：

  10.1023/a:1013262120747

文献信息

• SYNTHESE SYMMETRISCHER, MAKROCYCLISCHER PHOSPHORAMIDITE
  作者：I. Bauer、W. D. Habicher、P. G. Jones、H. Thönnessen、R. Schmutzler

  DOI：10.1080/10426509808045481

  日期：1998.12.1

  The reaction of phosphorous ester diamide 1 with bisphenol 2 did not lead to the expected asymmetric macrocycle 3 but instead in low yield to the symmetric macrocycle 4. The structure of the trans-isomer of 4 was determined by X-ray diffractometry. The same phenomenon was observed in the reaction of phosphorous ester diamide 5 with bisphenol 6, affording the symmetric macrocycle 7 as a mixture of cis-and trans-isomers. These results can only be explained by transesterification reactions which occur prior to the esterification of the phosphorous amide function.