[Fe(bis[2-(dimethylamino)ethyl]-(2-pyridylmethyl)amine)(NCS)2] | 1319205-41-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Fe(bis[2-(dimethylamino)ethyl]-(2-pyridylmethyl)amine)(NCS)2]
• CAS: 1319205-41-8
• 化学式: C₁₆H₂₆FeN₆S₂
• 分子量: 422.402
• InChiKey: LOKVYHRENJYHQT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Fe(py)4(NCS)2 、 bis(2-dimethylaminoethyl)(2-pyridylmethyl)amine 以 丙酮 为溶剂， 以59%的产率得到[Fe(bis[2-(dimethylamino)ethyl]-(2-pyridylmethyl)amine)(NCS)2]
  参考文献：
  名称：

  Synthesis, characterization and properties of iron(II) complexes with a series of tripodal ligands based on the parent ligand tris(2-pyridylmethyl)amine

  摘要：

  Iron(II) complexes of the type [Fe(L)(NCS)(2)] with the tripodal ligand apme (apme = N-1-(2-aminoethyl)-N-1-(2-pyridyl-methyl)-1,2-ethanediamine) as well as with its derivatives were prepared and structurally characterized. The bond distances thus obtained showed that all complexes investigated were high-spin at the respective temperature. Furthermore [Fe(Me(4)apme)(NCS)(2)] was analyzed using Mossbauer spectroscopy that showed that this complex remains in its high-spin state over the entire temperature range. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.062