trans-4,4'-benzophenone-bis[(iodo)bis(methyldiphenylphosphine)]diplatinum(II) | 309710-76-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: trans-4,4'-benzophenone-bis[(iodo)bis(methyldiphenylphosphine)]diplatinum(II)
• 英文别名: di(phenyl)methanone;iodoplatinum(1+);methyl(diphenyl)phosphane
• CAS: 309710-76-7
• 化学式: C₆₅H₆₀I₂OP₄Pt₂
• 分子量: 1625.05
• InChiKey: WMPHNCMOUUBRJJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  烟酸 、 trans-4,4'-benzophenone-bis[(iodo)bis(methyldiphenylphosphine)]diplatinum(II) 、 silver trifluoromethanesulfonate 以 二氯甲烷 为溶剂， 以97%的产率得到trans-4,4'-benzophenone-bis[(nicotinic acid)bis(methyldiphenylphosphine)]diplatinum(II) bis(triflate)
  参考文献：
  名称：

  Dinuclear organoplatinum(II)-methyldiphenylphosphine complexes of nicotinic acid

  摘要：

  The preparation and characterisation of a series of novel, dinuclear organoplatinum(II) complexes of methyldiphenylphosphine, trans-[Pt(PMePh2)(2)(C5H4N(CO2H))-mu-aryl-Pt(PMePh2)(2)(C5H4N(CO2H))](OTf)(2) (aryl = phenyl, 4,4'-biphenyl, 4,4 "-p-terphenyl, or 4,4'-benzophenone; OTf = triflate), in which nicotinic acid acts a nitrogen-donor ligand are described. The key structural feature of each complex is the presence of a carboxylic acid group at each end of the molecule. This allows for their association via intermolecular hydrogen-bonds in low polarity solvents. The complexes are potentially useful tectons (building blocks) for the construction of metal-containing supramolecular assemblies. (C) 2000 Published by Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00375-2
• 作为产物：
  描述：

  tetrakis(methyldiphenylphosphine)platinum(0) 、 双(4-碘苯基)甲酮 以 甲苯 为溶剂， 以96%的产率得到trans-4,4'-benzophenone-bis[(iodo)bis(methyldiphenylphosphine)]diplatinum(II)
  参考文献：
  名称：

  Dinuclear organoplatinum(II)-methyldiphenylphosphine complexes of nicotinic acid

  摘要：

  The preparation and characterisation of a series of novel, dinuclear organoplatinum(II) complexes of methyldiphenylphosphine, trans-[Pt(PMePh2)(2)(C5H4N(CO2H))-mu-aryl-Pt(PMePh2)(2)(C5H4N(CO2H))](OTf)(2) (aryl = phenyl, 4,4'-biphenyl, 4,4 "-p-terphenyl, or 4,4'-benzophenone; OTf = triflate), in which nicotinic acid acts a nitrogen-donor ligand are described. The key structural feature of each complex is the presence of a carboxylic acid group at each end of the molecule. This allows for their association via intermolecular hydrogen-bonds in low polarity solvents. The complexes are potentially useful tectons (building blocks) for the construction of metal-containing supramolecular assemblies. (C) 2000 Published by Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(00)00375-2