[(η5-thiophene)bis(triphenylphosphine)(methyl)ruthenium][AlCl2Me2] | 436864-12-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(η5-thiophene)bis(triphenylphosphine)(methyl)ruthenium][AlCl2Me2]
• 英文别名: carbanide;dichloroalumanylium;ruthenium(2+);thiophene;triphenylphosphane
• CAS: 436864-12-9
• 化学式: C₂H₆AlCl₂*C₄₁H₃₇P₂RuS
• 分子量: 852.785
• InChiKey: VUZPIVLVQCHEHL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  10.98
• 重原子数：
  50
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  噻吩 、 tris(triphenylphosphine)ruthenium(II) chloride 、 三甲基铝 以 正己烷 为溶剂， 以72%的产率得到[(η5-thiophene)bis(triphenylphosphine)(methyl)ruthenium][AlCl2Me2]
  参考文献：
  名称：

  One-Pot Synthesis of (η⁶-Arene)bis(triphenylphosphine)(methyl)ruthenium(II) Cations. X-ray Structures of [(η⁶-C₆H₆)Ru(Me)(PPh₃)₂][AlCl₂Me₂] and the η⁵-Thiophene Analogue

  摘要：

  We report one-pot syntheses for a series of complexes of the type [(eta(6)-arene)(RuMe)-Me-Pi(PPh3)(2)][AlCl2- Me-2]in high yields and X-ray structures of the eta(6)-C6H6 and eta(5)-thiophene derivatives. Other derivatives include fluorobenzene and mesitylene complexes, and all of the complexes are synthesized by addition of AlMe3 to RuCl2-(PPh3)(3) in the neat arene solvent or in an admixture with hexane for thiophene and fluorobenzene.

  DOI：

  10.1021/om0200860