6,6'-di(p-tolyl)-2,2'-bipyridine | 86696-23-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 6,6'-di(p-tolyl)-2,2'-bipyridine
• 英文别名: 2-(4-Methylphenyl)-6-[6-(4-methylphenyl)pyridin-2-yl]pyridine
• CAS: 86696-23-3
• 化学式: C₂₄H₂₀N₂
• 分子量: 336.436
• InChiKey: AXCBGKLVOSBGKE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  26
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  6,6'-di(p-tolyl)-2,2'-bipyridine 在 2,3,4,5,6-五氟苯乙烯 、 氢气 、 bis(pentafluorophenyl)borane 作用下， 以 甲苯 为溶剂， 100.0 ℃ 、5.0 MPa 条件下， 反应 20.0h， 以75%的产率得到cis-6,6'-di(p-tolyl)-2,2'-bipiperidine
  参考文献：
  名称：

  Metal-Free Borane-Catalyzed Highly Stereoselective Hydrogenation of Pyridines

  摘要：

  A metal-free direct hydrogenation of pyridines was successfully realized by using homogeneous borane catalysts generated from alkenes and HB(C6F5)(2) via in situ hydroboration. The reaction affords a broad range of piperidines in high yields with excellent cis stereoselectivities.

  DOI：

  10.1021/ja406761j

文献信息

• ORGANIC COMPOUND, CHARGE TRANSPORT MATERIAL AND ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Iida Koichiro

  公开号：US20090021146A1

  公开（公告）日：2009-01-22

  An organic compound is represented by following Formula (I): wherein Cz 1 and Cz 2 may be the same as or different from each other and each represent a carbazolyl group; Q 1 and Q 2 may be the same as or different from each other and each represent a direct bond or an arbitrary linkage group; and Cz 1 , Cz 2 , Q 1 , Q 2 , Ring B 1 and Ring B 2 may each be substituted. The organic compound and charge transporting material show both excellent hole transporting ability and excellent electron transporting ability and have satisfactory durability against electric oxidation/reduction and a high triplet excitation level. An organic electroluminescent device using the organic compound emits light with a high efficiency and is highly stably driven.
• MONOAMINE COMPOUND, CHARGE-TRANSPORTING MATERIAL, AND ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Yabe Masayoshi

  公开号：US20090230846A1

  公开（公告）日：2009-09-17

  The present invention provides an organic electroluminescent device exhibiting a long life, a high luminance, and a high efficiency. An organic electroluminescent device comprising on a substrate an anode, a hole transport layer, an organic light-emitting layer, and a cathode, wherein the organic light-emitting layer contains an organic compound having a pyridine ring, a pyrazine ring, or a triazine ring as a partial structure and the hole transport layer contains a monoamine compound represented by the following formula (I): wherein R 1 to R 9 represent a hydrogen atom, an aryl group, or an alkyl group; R 1 to R 9 may be the same or different from each other; and R 1 to R 9 may further have an aryl group or an alkyl group as a substituent in the case where R 1 to R 9 are an aryl group or an alkyl group.
• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Igarashi Tatsuya

  公开号：US20100026174A1

  公开（公告）日：2010-02-04

  An organic electroluminescent device is provided and includes: a pair of electrodes; and at least one organic layer between the pair of electrodes, the at least one organic layer including a light-emitting layer. The at least one organic layer includes at least one layer containing an indole derivative represented by formula (1), and the light-emitting layer includes a platinum complex phosphorescent material having a tetradentate ligand. R 101 , R 102 , R 103 , R 104 , R 105 , R 106 and R 107 each independently represents a hydrogen atom or a substituent, provided that R 102 and R 103 are not bonded to each other to form an aromatic condensed ring.
• US8168307B2
  申请人：——

  公开号：US8168307B2

  公开（公告）日：2012-05-01
• US8337999B2
  申请人：——

  公开号：US8337999B2

  公开（公告）日：2012-12-25