1-[(10-(3-methylenephenyl))-5,15-bis(pentafluorophenyl)copper-(III)corrole]-4-[(10-(4-oxymethylene))-5,15-bis(pentafluorophenyl)-iron(III)corrole(bis(acetonitrile))]triazole | 1620028-05-8

• 分子结构分类: 有机化合物
• 英文名称: 1-[(10-(3-methylenephenyl))-5,15-bis(pentafluorophenyl)copper-(III)corrole]-4-[(10-(4-oxymethylene))-5,15-bis(pentafluorophenyl)-iron(III)corrole(bis(acetonitrile))]triazole
• CAS: 1620028-05-8
• 化学式: C₈₂H₃₅CuF₂₀FeN₁₃O
• 分子量: 1717.63
• InChiKey: YBNUKMQWPRXQMC-NJCRXFJISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(III) 5,15-bis(pentafluorophenyl)-10-(3-azidomethylphenyl)corrole 、 iron(III) 5,15-bis(pentafluorophenyl)-10-(4-propargyloxyphenyl)corrole bis(diethyl ether) 在 copper (I) acetate 作用下， 以 二氯甲烷 为溶剂， 以54%的产率得到1-[(10-(3-methylenephenyl))-5,15-bis(pentafluorophenyl)copper-(III)corrole]-4-[(10-(4-oxymethylene))-5,15-bis(pentafluorophenyl)-iron(III)corrole(bis(acetonitrile))]triazole
  参考文献：
  名称：

  Corroles That “Click”: Modular Synthesis of Azido- and Propargyl-Functionalized Metallocorrole Complexes and Convergent Synthesis of a Bis-corrole Scaffold

  摘要：

  Bis-corroles have been prepared through a convergent synthesis using a copper-catalyzed azide-alkyne cycloaddition. Synthesis of the final homo- and heterobimetallic complexes has been achieved in three to four steps from commercially available materials in good overall yield. Meso-substituted corroles functionalized with a single azido or propargyl group were used as key starting materials. (C6F5)(2)(p-O(CH2CCH)Ph)corroleH(3) (I) and ((C6F5)2(m-CH2N3)Ph)corroleH(3) (3) were metalated with copper or iron and attached by Huisgen azide-alkyne cycloaddition ("click" reaction) first to small substrates and then to each other, demonstrating a convergent synthesis of bimetallic bis-corrole molecules.

  DOI：

  10.1021/ic500714h