nickel(0) 4,6,10,12,16,18,22,24-octahydroxy-2,8,14,20-tetra[4-(1,2,3-dioxothiophosphoryloxy)phenyl]-5,11,17,23-tetramethylpentacyclo[19.3.1^13,7.1^9,13.1^15,19]octacosa-1(25),3,-5,7(28),9,11,13(27),15,17,19(26),21,23-dodecaenylate | 1443753-76-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: nickel(0) 4,6,10,12,16,18,22,24-octahydroxy-2,8,14,20-tetra[4-(1,2,3-dioxothiophosphoryloxy)phenyl]-5,11,17,23-tetramethylpentacyclo[19.3.1^13,7.1^9,13.1^15,19]octacosa-1(25),3,-5,7(28),9,11,13(27),15,17,19(26),21,23-dodecaenylate
• CAS: 1443753-76-1
• 化学式: C₆₄H₆₀O₂₀P₄S₄*Ni
• 分子量: 1460.02
• InChiKey: CEMXPYXCIQOTJY-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  nickel(II) bromide trihydrate 、 以 N,N-二甲基甲酰胺 为溶剂， 以85.1%的产率得到nickel(0) 4,6,10,12,16,18,22,24-octahydroxy-2,8,14,20-tetra[4-(1,2,3-dioxothiophosphoryloxy)phenyl]-5,11,17,23-tetramethylpentacyclo[19.3.1^13,7.1^9,13.1^15,19]octacosa-1(25),3,-5,7(28),9,11,13(27),15,17,19(26),21,23-dodecaenylate
  参考文献：
  名称：

  Electrochemical synthesis of the calix[4]resorcinol nickel complexes modified with thiophosphoryl fragments

  摘要：

  Nickel complexes of 1:1 composition with calix[4]resorcinols (L) modified with thiophosphyl fragments were synthesized. In the process of electrochemical reduction these complexes are capable of providing spherical homogeneous Ni(0)L particles with a narrow size distribution, stable both on the electrode and in the solution. The redox properties of the metal complexes were studied. The dimensions of the complexes obtained were estimated using the atomic force microscope (AFM) equipped with an electrochemical attachment.

  DOI：

  10.1134/s1070363213040099