[Fe(2,3,5,6-tetrakis(2-pyridyl)pyrazine)2](2+) | 62460-25-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Fe(2,3,5,6-tetrakis(2-pyridyl)pyrazine)2](2+)
• 英文别名: [Fe(TPPZ)2](2+)
• CAS: 62460-25-7
• 化学式: C₄₈H₃₂FeN₁₂
• 分子量: 832.709
• InChiKey: OXRUSGZNKNWSFN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  四-2-吡啶基吡嗪 、 iron(II) acetate 在 HCl 作用下， 以 盐酸 、 水 为溶剂， 生成 [Fe(2,3,5,6-tetrakis(2-pyridyl)pyrazine)2](2+)
  参考文献：
  名称：

  Fe–N /C electrocatalysts synthesized by pyrolysis of Fe(II)–2,3,5,6-tetra(2-pyridyl)pyrazine complex for PEM fuel cell oxygen reduction reaction

  摘要：

  2,3,5,6-Tetra(2-pyridyl)pyrazine (TPPZ) was employed as a ligand to prepare an iron(II) complex (Fe-TPPZ) that served as a precursor to synthesize carbon-supported catalysts (Fe-N-x/C) through heattreatment at 600, 700, 800 and 900 degrees C under N-2 atmosphere. Both the structure and composition of the synthesized Fe-N-x/C were analyzed by X-ray diffraction and energy-dispersive X-ray microanalysis, respectively. The rotating disk and ring-disk electrode measurements showed that these catalysts have strong ORR activity with an overall 4-electron transfer process through a (2 + 2)-electron transfer mechanism, which was assigned to the catalytic function of the Fe-N-x center. A study on the heat-treatment temperature on the ORR activity showed that 800 degrees C is the optimal temperature for the synthesized catalysts. Furthermore, the effect of both catalyst and Nafion (R) ionomer loadings in the catalyst layer on the corresponding ORR activity was also investigated. The kinetic parameters such as the chemical reaction rate between O-2 and Fe-N-x/C (adduct formation reaction), the rate constant for the rate-determining step (RDS), and the electron numbers in the ORR, were obtained. The methanol tolerance of the catalyst was also tested. To validate the ORR activity, a membrane electrode assembly in which the cathode catalyst layer contained Fe-N-x/C was constructed and tested in a real fuel cell. The results obtained are encouraging when compared with similar non-noble catalysts. (C) 2011 Published by Elsevier Ltd.

  DOI：

  10.1016/j.electacta.2011.03.059