bis(μ-2-[5-[(pyridin-4-ylmethyl)sulfanyl]-1,3,4-oxadiazol-2-yl]phenolato)bis(acetylacetonato)copper(II) | 1310356-28-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(μ-2-[5-[(pyridin-4-ylmethyl)sulfanyl]-1,3,4-oxadiazol-2-yl]phenolato)bis(acetylacetonato)copper(II)
• CAS: 1310356-28-5
• 化学式: C₃₈H₃₄Cu₂N₆O₈S₂
• 分子量: 893.947
• InChiKey: NPAYUUZEDZOEBL-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  copper acetylacetonate 、 2-[5-[(pyridin-4-ylmethyl)sulfanyl]-1,3,4-oxadiazol-2-yl]phenol 以 甲醇 、 二氯甲烷 为溶剂， 以75%的产率得到bis(μ-2-[5-[(pyridin-4-ylmethyl)sulfanyl]-1,3,4-oxadiazol-2-yl]phenolato)bis(acetylacetonato)copper(II)
  参考文献：
  名称：

  Bis(μ-2-{5-[(pyridin-4-ylmethyl)sulfanyl]-1,3,4-oxadiazol-2-yl}phenolato)bis[(acetylacetonato)copper(II)]: a novel binuclear metallocycle

  摘要：

  The new asymmetric ligand 2-{5-[(pyridin-4-ylmethyl)sulfanyl]-1,3,4-oxadiazol-3-yl}phenol (HL) has been used to synthesize the novel discrete title binuclear metallocycle, [Cu-2(C14H10N3O2S)(2)(C5H7O2)(2)] or Cu-2 L (2)(acac)(2) (acac is acetylacetonate). Each CuII centre is five-coordinate and adopts a square-pyramidal geometry. Two ligands are connected by two CuII cations to form the dinuclear metallocycle, which lies across a crystallographic inversion centre. Discrete molecules are linked into a two-dimensional structure through weak Cu...S, C-H...pi and pi-pi interactions.

  DOI：

  10.1107/s0108270111006640