Pd(4,7-diphenyl-1,10-phenanthroline)(methoxycarbonyl)2 | 214557-71-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: Pd(4,7-diphenyl-1,10-phenanthroline)(methoxycarbonyl)2
• CAS: 214557-71-8
• 化学式: C₂₈H₂₂N₂O₄Pd
• 分子量: 556.914
• InChiKey: OLENTFYVENKALY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(carbomethoxy)palladium bipyridine 、 4,7-二苯基-1,10-菲罗啉 以 甲醇 为溶剂， 以85%的产率得到Pd(4,7-diphenyl-1,10-phenanthroline)(methoxycarbonyl)2
  参考文献：
  名称：

  New palladium (substituted 1,10-phenanthroline) bis(methoxycarbonyl) complexes [Pd(L–L)(CO2CH3)2]: preparation and structural features

  摘要：

  New complexes of general formula Pd(L-L)(CO2CH3)(2) (L-L = 1,10-phenanthroline (1) under bar; 2,9-dimethyl-1,10-phenanthroline (2) under bar; 4,7-dimethyl-1,10-phenanthroline (3) under bar; 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (4) under bar, 3,4,7,8-tetramethyl-1,10-phenanthrorine (5) under bar; and 4,7-diphenyl-1,10-phenanthroline (6) under bar) were prepared either by exchange reaction between Pd(bipyridine)(CO2CH3)(2) (7) under bar and the appropriate free ligand or by reacting Pd(L-L)Cl-2 suspended in MeOH under carbon monoxide, at room temperature, in the presence of a base. The structure of (1) under bar was determined ab initio from X-ray powder diffraction data by using a simulated annealing technique and refined by the Rietveld method. (1) under bar crystallizes in the orthorhombic Pbca space group with cell parameters a = 8.0787(4), b = 16.2797(8), c = 22.843(1) Angstrom and Z = 8. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00742-6