[Ag(OBt)(HOBt)](n) | 1166854-62-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并三唑类
• 英文名称: [Ag(OBt)(HOBt)](n)
• 英文别名: [Ag(1-hydroxybenzotriazolato)(1-hydroxybenzotriazole)](n)
• CAS: 1166854-62-1
• 化学式: Ag*C₆H₄N₃O*C₆H₅N₃O
• 分子量: 377.111
• InChiKey: NIZXYMIBWYISTI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.44
• 重原子数：
  21.0
• 可旋转键数：
  0.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  104.71
• 氢给体数：
  1.0
• 氢受体数：
  8.0

反应信息

• 作为产物：
  描述：

  1-羟基苯并三唑 、 silver nitrate 在 NaOH 作用下， 以 水 为溶剂， 以62%的产率得到[Ag(OBt)(HOBt)](n)
  参考文献：
  名称：

  Synthesis, structures, luminescence/magnetic properties of complexes of the M/1-hydroxybenzotriazole, M=cobalt, nickel, silver, zinc and copper

  摘要：

  Five novel complexes, Co(OBt)(2) center dot 7H(2)O (1) (OBt = 1-hydroxybenzotriazole ion), Ni-3(OBt)(6) center dot 6H(2)O (2), [Ag(OBt)(HOBt)](n) (3), [Zn(OBt)(2)](n) (4) and [Cu-2(OBt)(4) center dot 3H(2)O](n) (5) were synthesized by hydrothermal method and characterized by elemental analysis, IR spectroscopy, TGA, XRPD, and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction indicate that 1-5 are zero-dimensional (0D), zero-dimensional, one-dimensional (1D), and three-dimensional (3D) frameworks, respectively. In particular, 3 is twin crystal; 4 possesses of double-stranded chains; 5 crystallizes in orthorhombic space group P2(1)2(1)2(1) with a helical chain in its structure. The luminescence properties and the magnetic properties of the five complexes were investigated. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.01.044