N-[2-methyl-4-[3-methyl-4-(pyridin-4-ylmethylideneamino)phenyl]phenyl]-1-pyridin-4-ylmethanimine | 1042676-56-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-[2-methyl-4-[3-methyl-4-(pyridin-4-ylmethylideneamino)phenyl]phenyl]-1-pyridin-4-ylmethanimine
• CAS: 1042676-56-1
• 化学式: C₂₆H₂₂N₄
• 分子量: 390.487
• InChiKey: AEPKZKDPEJFMCQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  30
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  50.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  甲醇 、 cadmium(II) perchlorate hexahydrate 、 N-[2-methyl-4-[3-methyl-4-(pyridin-4-ylmethylideneamino)phenyl]phenyl]-1-pyridin-4-ylmethanimine 以 甲醇 、 苯 为溶剂， 以53%的产率得到
  参考文献：
  名称：

  Connecting modes of linking ligands containing different terminal groups (pyridyl–amine or pyridyl–pyridyl): Preparation and structures of {[Cd(L1)2(OH2)2]·(ClO4)2·(C6H6)}∞, {[Cd(L2)2(ClO4)2]·(CH3OH)2}∞, {[Cd(L3)2(OH2)2]·(ClO4)2}∞, and [Cd(L4)2(CH3OH)2(ClO4)2] {(m-py)–CHN–(CH3)C6H3–C6H3(CH3)–NH2 (m=3 (L1) or 4 (L2)); (n-py)–CHN–(CH3)C6H3–C6H3(CH3)–NCH–(n-py); (n=3 (L3) or 4 (L4))}

  摘要：

  We prepared four potential linking ligands, [(3-py)-CH=N-(CH3)C6H3-C6H3-(CH3)-NH2, L1], [(4-py)-CH=N-(CH3)C6H3-C6H3(CH3)-NH2, L2], [(3-py)-CH=N-(CH3)C6H3-C6H3(CH3)-N=CH-(3-py), L3], and [(4-py)-CH=N-(CH3)C6H3-C6H3(CH3)-N=CH-(4-py), L4], all of which contain an intervening biphenyl fragment. Whereas ligands L1 and L2 have two types of terminal groups (pyridyl-amine), ligands B and LA have a single type of terminal groups (pyridyi-pyridyl). Ligands L1-L4 reacted with cadmium nitrate to produce ([Cd(L1)(2)(OH2)(2)]center dot(ClO4)(2)center dot(C6H6)}(infinity) (1), {[Cd(L2)(2)(ClO4)(2)]center dot(CH3OH)(2)}(infinity) (2). ([Cd(L3)(2) (OH2)(2)]center dot(ClO4)(2)}(infinity) (3), and [Cd(L4)(2)(CH3OH)(2)(ClO4)(2)] (4), respectively. Whereas compounds 1-3 are 1-dimensional coordination polymers, compound 4 is a discrete molecular species. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2009.06.044