6-hydrazinyl-2-(4-propoxyphenyl)benzo[de]isoquinoline-1,3-dione | 1154534-55-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: 6-hydrazinyl-2-(4-propoxyphenyl)benzo[de]isoquinoline-1,3-dione
• CAS: 1154534-55-0
• 化学式: C₂₁H₁₉N₃O₃
• 分子量: 361.4
• InChiKey: KQTNTHNFKNRJMS-UHFFFAOYSA-N

物化性质

• 沸点：
  647.7±55.0 °C(predicted)
• 密度：
  1.366±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.71
• 重原子数：
  27.0
• 可旋转键数：
  5.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  84.66
• 氢给体数：
  2.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  6-hydrazinyl-2-(4-propoxyphenyl)benzo[de]isoquinoline-1,3-dione 、 4-[(4-乙烯基苯基)甲氧基]苯甲醛 以 甲乙醚 为溶剂， 反应 4.0h， 生成 2-(4-propoxyphenyl)-6-(2-(4-((4-vinylbenzyl)oxy)benzylidene)hydrazineyl)-1H-benzo[de]isoquinoline-1,3(2H)-dione
  参考文献：
  名称：

  The synthesis and NLO properties of 1,8-naphthalimide derivatives for both femtosecond and nanosecond laser pulses

  摘要：

  Four 1,8-naphthalimide derivatives were synthesized for new nonlinear optical(NLO) materials. Hydrazone group as a p-pi structure was introduced into the molecule to extend conjugation and produce NLO properties. Their linear and nonlinear optical (NLO) properties were studied in details. The results show that these compounds possess strong excited-state absorption (ESA) properties and optical limiting with nanosecond laser pulses at 532 nm. Moreover, they also preserve the luminescence originated from naphthalimide and two-photon absorption (TPA) behaviour which can be observed under femtosecond laser pulses ranged from 750 to 870 nm. The broad-band optcial limiting properties of these compounds indicate that they can be potentially applicated in optical limiting materials. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2012.01.001
• 作为产物：
  描述：

  1-硝基-4-丙氧基-苯 在 盐酸 、 铁粉 作用下， 以 乙醇 为溶剂， 生成 6-hydrazinyl-2-(4-propoxyphenyl)benzo[de]isoquinoline-1,3-dione
  参考文献：
  名称：

  The synthesis and NLO properties of 1,8-naphthalimide derivatives for both femtosecond and nanosecond laser pulses

  摘要：

  Four 1,8-naphthalimide derivatives were synthesized for new nonlinear optical(NLO) materials. Hydrazone group as a p-pi structure was introduced into the molecule to extend conjugation and produce NLO properties. Their linear and nonlinear optical (NLO) properties were studied in details. The results show that these compounds possess strong excited-state absorption (ESA) properties and optical limiting with nanosecond laser pulses at 532 nm. Moreover, they also preserve the luminescence originated from naphthalimide and two-photon absorption (TPA) behaviour which can be observed under femtosecond laser pulses ranged from 750 to 870 nm. The broad-band optcial limiting properties of these compounds indicate that they can be potentially applicated in optical limiting materials. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2012.01.001